高等学校化学学报

高等学校化学学报

• 研究论文 • 上一篇    

甲酸-草酸共配体低维磁性镱配合物的构筑及磁性研究

翟晓璐1,吕云1,李会1,黄科科2,王艳红1,卢红成1，3   

  1. 1. 华中科技大学化学与化工学院, 能量转换与存储材料化学教育部重点实验室, 材料化学与服役失效湖北省重点实验室  2. 无机合成与制备化学全国重点实验室, 吉林大学化学学院  3. 华中科技大学国家脉冲强磁场科学中心
  • 收稿日期:2026-05-10 修回日期:2026-05-28 出版日期:2026-05-31 发布日期:2026-05-31
  • 通讯作者: 卢红成 E-mail:yhw1006@hust.edu.cn
  • 基金资助:
     国家自然科学基金(批准号: 22422111)资助

Construction and Magnetic Properties of Low-Dimensional Ytterbium(III) Coordination Polymers Based on Formate and Oxalate Co-Ligands

ZHAI　Xiaolu1， LV　Yun1， LI　Hui1， HUANG　Keke2， WANG　Yanhong1*， LU　Hongcheng1，3   

  1. 1. School of Chemistry and Chemical Engineering， Key Laboratory of Material Chemistry for Energy Conversion and Storage， Ministry of Education， Hubei Key Laboratory of Materials Chemistry and Service Failure， Huazhong University of Science and Technology 2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry， College of Chemistry， Jilin University 3. Wuhan National High Magnetic Field Center， Huazhong University of Science and Technology
  • Received:2026-05-10 Revised:2026-05-28 Online:2026-05-31 Published:2026-05-31
  • Contact: Hongcheng LU E-mail:yhw1006@hust.edu.cn
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.22422111)

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摘要： 采用溶剂热法合成了一例新型层状磁性镱配合物Yb(HCOO)(C2O4)(1,10-phen) (1,10-phen = 邻菲罗啉)，并利用X射线衍射、红外、热重和磁化率等测试对其晶体结构和磁性性能进行了表征.单晶结构分析表明，该配合物中磁性离子Yb3+通过甲酸根与草酸根连接形成四方磁晶格层，层间通过邻菲罗啉配体隔开.磁性测试结果显示，配合物中Yb3+间以反铁磁相互作用占主导，且在温度低至2 K时未出现长程磁有序.本研究为构筑具有低维磁性的稀土配合物提供了新的合成策略.

关键词: 低维磁性, 晶体结构, 镱配合物, 溶剂热法

Abstract: A novel layered magnetic ytterbium coordination compound, Yb(HCOO)(C2O4)(1,10-phen) (1,10-phen = 1,10-phenanthroline), has been successfully synthesized via a solvothermal method. Its crystal structure and magnetic properties were characterized by X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, and magnetic susceptibility measurements. Single-crystal structure analysis reveals that the magnetic Yb3+ ions are connected by formate and oxalate ligands to form a square magnetic lattice, with adjacent layers separated by 1,10-phen ligands. Magnetic measurements show that the dominate interaction between the Yb3+ ions is antiferromagnetic, and no long-range magnetic order is observed down to 2?K. This study provides a new synthetic strategy for constructing low-dimensional magnetic rare-earth coordination compounds.

Key words: Low-dimensional magnetism, Crystal structure, Ytterbium coordination compound, Solvothermal method

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