高等学校化学学报 ›› 2021, Vol. 42 ›› Issue (2): 397.doi: 10.7503/cjcu20200584
黄大朋, 于浩海, 张怀金
收稿日期:
2020-08-21
出版日期:
2021-02-10
发布日期:
2020-12-25
通讯作者:
于浩海
E-mail:haohaiyu@sdu.edu.cn;huaijinzhang@sdu.edu.cn
作者简介:
张怀金, 男, 博士, 教授, 主要从事人工晶体生长和性能研究. E-mail: 基金资助:
HUANG Dapeng, YU Haohai, ZHANG Huaijin
Received:
2020-08-21
Online:
2021-02-10
Published:
2020-12-25
Contact:
YU Haohai
E-mail:haohaiyu@sdu.edu.cn;huaijinzhang@sdu.edu.cn
Supported by:
摘要:
过渡金属碳化物、 氮化物或碳氮化物(MXenes)具有丰富的元素组成和结构可调性, 显示出丰富的物理化学性质和巨大的应用潜力. 本文以此类材料的基本光学特性为基础, 从光子发射、 透明导电及储能、 非线性光学、 表面等离激元及拉曼增强、 光热转化、 光催化及光响应等光学相关领域展开分析和综述. 并对此二维材料相关应用的未来发展及机遇作了简单评述, 以期为进一步的研究提供参考.
中图分类号:
TrendMD:
黄大朋, 于浩海, 张怀金. MXenes材料的光学特性及相关研究进展. 高等学校化学学报, 2021, 42(2): 397.
HUANG Dapeng, YU Haohai, ZHANG Huaijin. Optical Properties and Related Research Progress of MXenes. Chem. J. Chinese Universities, 2021, 42(2): 397.
Fig.1 Crystal structures of the 211(A), 312(B), and 413(C) MAX phases and high?angle annular dark field TEM image, acquired along the [112ˉ0] zone axis of Ti3SiC2, showing the twinned structure and the resulting characteristic “zig?zag” stacking of MAX phases(D)[4]Copyright 2010, Elsevier.
Fig.2 Calculated imaginary part of the dielectric function(A)(inset shows the real part) and absorption coefficient for Ti3C2?MXene(B)[8]The two nonzero components of the dielectric tensor εxx(ω) and εzz(ω) for electric field perpendicular(E||x) and parallel(E||z) to c?axis are represented by the solid red and dashed blue line.Copyright 2014, Elsevier.
Fig.3 Real(ε1)(A) and imaginary(ε2)(B) part of dielectric function as a function of photon energy for Ti3C2T2?MXene; refractive index, n(C), and the extinction coefficient, k(D), as a function of photon energy for Ti3C2T2 MXene and absorption spectra of Ti3C2T2?MXene for small(E) and larger(F) range of photon energy[12]Ti3C2: solid?black curves; Ti3C2F2: dashed?red curves; Ti3C2O2: dotted?green curves; Ti3C2(OH)2: dash?dotted?blue curves. Shaded area shows the visible range of the spectrum.Copyright 2016, American Institute of Physics.
Fig.4 Schematic of TiO2 clusters interspersed throughout the Ti3C2?MXene flake, and the diagrams of PL transitions at perfect Ti3C2?MXene and defective TiO2(A), PL spectra of Ti3C2?MXene without(left) and with modification(right) at the excitation wavelengths of 405 nm, 532 nm and 632.8 nm(B)[15], schematic diagram of preparation of MXenes quantum dots(MQDs)(C) and UV?Vis spectra(solid line), PLE(dashed line), and PL spectra(solid line, λex=320 nm) of MQD in aqueous solutions(D)[16](A, B) Copyright 2019, Elsevier. (C, D) Copyright 2017, John Wiley and sons.
Fig.5 Fluorescent lifetime of s?MQDs(a), f?MQDs(b), and e?MQDs(c)(A), PL intensity of f?MQDs excited at 377 nm upon addition of Fe3+ ions ranging from 0 to 750×10-6 mol/L(B)[17], emission spectra from the V2C MQD colloid for different pump fluences(C), plot of the calculated CIE coordinates of emission spectra under different pumping fluence(D)[18], schematic illustration of the emission, and under the conditions of high pressure(E)[19], and fluorescence emission spectra of the prepared N?MQDs(160 ℃) at different excitation wavelengths and photographs under UV light(365 nm)(inset)(F)[20](A, B) Copyright 2018, John Wiley and sons; (C, D) Copyright 2019, John Wiley and sons; (E) Copyright 2019, John Wiley and sons; (F) Copyright 2018, Royal Society of Chemistry.
Fig.6 UV?Vis?NIR linear optical attenuation of spin?coated Ti3C2?MXene films as a function of deposition thickness(A), calculated imaginary(top) and real(bottom) dielectric dispersion based on the experimental results of (A)(B)[28], absorbance of Ti3C2?MXene features low optical attenuation at 550 nm compared to reduced graphene oxide(rGO)(C)[32], transmittance spectra and visual images(on right) for Ti3AlC2(I), Ti3C2?MXene(II), and Ti3C2?MXene?IC(III) films of 15 nm nominal thickness(D)[31], schematic diagram of the complementary inverter consisting of p?FET[WSe2/Ti2C(OH)xFy] and n?FET[MoS2/Ti2C(OH)xFy] devices(E)[35] and Ti3C2?MXene/n?Si heterostructure(F)[37](A, B) Copyright 2016, John Wiley and sons. (C) Copyright 2016, John Wiley and sons. (D) Copyright 2014, American Chemical Society. (E) Copyright 2016, John Wiley and sons. (F) Copyright 2017, John Wiley and sons.
Fig.7 Schematic demonstration of Ti3C2Tx MXene?based transparent, flexible solid?state supercapacitor and comparison of volumetric capacitance of Ti3C2Tx to other transparent film systems(A) and measured areal capacitance of various Ti3C2Tx films(B)[30]Copyright 2017, John Wiley and sons.
Fig.8 Z?scan nonlinear optical characterizations(A)[54], open aperture Z?scan characterizations of Ti3C2?MXene at wavelengths of 1064 nm(B), effective nonlinear absorption coefficient(βeff) as a function of pulse energy(Ep) at different wavelengths[53](C), inkjet printing schematic diagram(D); schematic diagrams of laser resonators with an inkjet?printed MXene saturable absorber(E), the output laser pulse durations(F)[56]; the nonreciprocal transmission characteristics(G)[54] and Ti3C2?MXene nanosheets?based all?optical switching(H)[63](B) Solid lines are the fitting results with a two?level energy system model. (H) The probe light can be modulated by the pump light to realize “ON” and “OFF” modes in all?optical switching.(A) Copyright 2018, John Wiley and sons. (B, C) Copyright 2017, John Wiley and sons. (D―F) Copyright 2018, John Wiley and sons. (G) Copyright 2018, John Wiley and sons. (H) Copyright 2018, John Wiley and sons.
Fig.9 Experimental —OH?terminated low?loss spectra recorded on Ti3C2T2 for different thicknesses(A), detailed view of the surface plasmon energy region(B)[67], the zero energy loss EEL spectra of a triangular Ti3C2?MXene flake[thickness: (7.5±0.04) nm](top), STEM?HAADF micrograph of the Ti3C2?MXene flake on a Si3N4 membrane(top inset), excited longitudinal SP, transversal SP, and interband transition distributions on the same Ti3C2Tx flake(bottom)(C)[32], schematic representation of the photodetector under illumination showing the migration process of the plasmon?assisted hot electrons toward the biased gold electrodes(D), photoresponse of a Mo2C?MXene thin film photodetector as a function of wavelength, under 0.7 V bias voltage(E)[68], schematic of a typical arrays of nanodisks made of Ti3C2?MXene(F), simulated absorption spectra comparison of unpatterned MXene film, MXene disk array on glass, and MXene disk array on Au/alumina(G)[33] and schematic diagram of spray?coated MXene SERS substrates for dye detection(H)[70](A) The spectra are normalized at 7 eV(labeled N) and are magnified by a factor of 10 above 3 eV; (B) insets: typical STEM?annular dark?field image of the samples; (E) inset: photograph of the photocurrent setup showing one of the investigated samples, illumination objective, and the contact electrodes; (G) incident light is TE polarized, angle of incidence is 20°.(A, B) Copyright 2014, American Physics Society. (C) Copyright 2018, American Chemical Society. (D, E) Copyright 2019, John Wiley and sons. (F, G) Copyright 2018, American Chemical Society. (H) Copyright 2017, American Chemical Society.
Fig.10 Experimental setup for droplet?based light?to?heat conversion experiment and schematic of droplet with laser irradiation(A), temperature?time course of PDMS modified PVDF membrane and MXene?PVDF membrane in air under 1?Sun illumination(B)[74], and schematic illustration of the synthesis of Ta4C3? MXene nanosheets, and in vivo PA/CT dual?mode imaging combined with photothermal therapy(C)[76](A, B) Copyright 2017, American Chemical Society.(C) Copyright 2018, John Wiley and sons.
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