自支撑镍纳米线阵列电极的制备及电催化性能

doi:10.7503/cjcu20180405

高等学校化学学报 ›› 2018, Vol. 39 ›› Issue (12): 2739.doi: 10.7503/cjcu20180405

自支撑镍纳米线阵列电极的制备及电催化性能

杜孟孟¹, 孙海军¹, 高山¹, 叶小利¹, 乔磊¹, 郭芬²()

1. 武汉第二船舶设计研究所, 武汉 430064
2. 武汉科技大学化学与化工学院, 煤转化与新型炭材料湖北省重点实验室, 武汉 430081

收稿日期:2018-06-04 出版日期:2018-11-04 发布日期:2018-11-04
作者简介:
联系人简介: 郭芬, 女, 博士, 讲师, 主要从事新能源材料与器件研究. E-mail: guofen@wust.edu.cn
基金资助:
湖北省自然科学基金(批准号: 2018CFB214)和煤转化与新型炭材料湖北省重点实验室开放基金(批准号: WKDM201710)资助.

Preparation and Electro-catalytic Property of Self-supported Nickel Nanowire Array Electrode^†

DU Mengmeng¹, SUN Haijun¹, GAO Shan¹, YE Xiaoli¹, QIAO Lei¹, GUO Fen^2,^*()

1. Wuhan Second Ship Design and Research Institute, Wuhan 430064, China
2. Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China

Received:2018-06-04 Online:2018-11-04 Published:2018-11-04
Contact: GUO Fen E-mail:guofen@wust.edu.cn
Supported by:
† Supported by the Natural Science Foundation of Hubei Province, China(No.2018CFB214) and the Open Fund from Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials, China(No.WKDM201710).

摘要/Abstract

摘要：

采用低熔点合金和多孔聚碳酸酯模板辅助制备了自支撑镍纳米线阵列电极, 并研究了其催化肼电氧化的性能. SEM, XRD和TEM测试结果表明, 该电极由镍平板和支撑在其上的镍纳米线阵列构成; 镍纳米线的絮状表面增加了电极的比表面积. 循环伏安和计时电位测试结果表明, 当肼的浓度为24.6 mmol/L时, 该电极的起始氧化电位低至-0.25 V, 氧化电流密度高达163 mA/cm²; 当肼浓度较低时, 肼电氧化反应和电极自身的Ni(OH)₂/NiOOH转化反应共存; 当肼浓度较高时, 仅发生肼电氧化反应; 肼的反应分级数约为1, 反应活化能为16.13~21.24 kJ/mol; 镍纳米线阵列电极的一体化、开放式结构使其电催化性能明显优于商业镍片和泡沫镍, 并表现出良好的稳定性.

关键词: 低熔点合金, 多孔模板, 纳米线阵列, 镍, 肼电氧化

Abstract:

A self-supporting nickel nanowire array(NNA) electrode was prepared by using the low-melting point alloy and porous polycarbonate template, and its catalytic performance toward hydrazine electro-oxidation was studied. SEM, XRD and TEM results show that the NNA electrode consists of a nickel plate and nickel nanowire arrays supported on it. The cotton-like surface of nickel nanowires provides the NNA electrode with the additional specific surface area. Cyclic voltammograms and chronopotential measurements show that when the concentration of hydrazine is 24.6 mmol/L, the onset oxidation potential of the electrode is as low as -0.25 V, and the oxidation current density is as high as 163 mA/cm². When the concentration of hydrazine is relatively low, the hydrazine electro-oxidation reaction and the Ni(OH)₂/NiOOH conversion reaction of the electrode coexist. When the concentration of hydrazine reaches a relatively high level, only hydrazine electro-oxidation occurs. The reaction order of hydrazine species approximately equals to 1, and the reaction activation energy is 16.13—21.24 kJ/mol. The integrated, open structure makes the NNA electrode show significantly better electrocatalytic performance than commercial nickel piece and nickel foam, and exhibit excellent stability.

Key words: Low-melting point alloy, Porous template, Nanowire array, Nickel, Hydrazine electro-oxidation

中图分类号:

O646

TrendMD:

杜孟孟, 孙海军, 高山, 叶小利, 乔磊, 郭芬. 自支撑镍纳米线阵列电极的制备及电催化性能. 高等学校化学学报, 2018, 39(12): 2739.

DU Mengmeng,SUN Haijun,GAO Shan,YE Xiaoli,QIAO Lei,GUO Fen. Preparation and Electro-catalytic Property of Self-supported Nickel Nanowire Array Electrode^†. Chem. J. Chinese Universities, 2018, 39(12): 2739.

图/表 7

Fig.1 Preparation process of nickel nanowire array electrode and physical photos of relevant materials

Fig.2 SEM lateral view of Ni plate-template-Ni nanowires composite(A) and SEM vertical view of Ni nanowire arrays at different magnifications(B—D)

Fig.3 TEM(A—C) and high resolution TEM(D) images of Ni nanowiresInset of (C) is the TEM image of Ni nanowire prepared utilizing dichloromethane as the solvent.

Fig.4 XRD patterns of Ni plate(a), template with Ni nanowires imbedding in it(b) and the bare template(c)

Fig.5 CV curves of self-supported Ni nanowire arrays, commercial Ni piece and Ni foam in 1.0 mol/L KOH(A) and 1.0 mol/L KOH + 24.6 mmol/L N2H4(D) solutions(scan rate: 10 mV/s), fast CV scans of Ni nanowire arrays in 1.0 mol/L KOH(B), plots of j derived from the current density at -0.3 V(B) versus scan rate(C), chronopotential curves of nickel nanowire arrays at diffe-rent current densities(E) and results for aging experiments recorded in 1.0 mol/L KOH + 24.6 mmol/L N2H4(F)

Fig.6 CV curves in 1.0 mol/L KOH+x mmol/L N2H4 solutions(x=0, 4.1, 8.2 and 12.3, scan rate: 10 mV/s)(A) and plots of lnjversus lncN2H4 at -0.15, 0.05 and 0.1 V(B)

Fig.7 CV curves at different temperatures in 1.0 mol/L KOH+ 24.6 mmol/L N2H4(scan rate: 10 mV/s)(A) and plots of lnj versus 1/T at -0.1—0.3 V(B)

参考文献 24

[1]	Wang J., Wei Z.D., Acta Phys. Chim. Sin.,2017, 33(5), 886—902
	(王俊, 魏子栋. 物理化学学报, 2017, 33(5), 886—902)
[2]	Kang H., Li S., Liu C., Guo W., Pan M., Chem. J. Chinese Universities,2017, 38(8), 1423—1430
	(康欢, 李赏, 刘畅, 郭伟, 潘牧. 高等学校化学学报, 2017, 38(8), 1423—1430)
[3]	Guo F., Ye K., Du M., Huang X., Cheng K., Wang G., Cao D., Electrochim. Acta,2016, 210, 474—482
[4]	Lee M.J., Kang J.S., Kang Y.S., Chung D.Y., Shin H., Ahn C.Y., Par K.S., Kim M.J., Kim S., Lee K.S., Sung Y.E., ACS Catal., 2016, 6(4), 2398—2407
[5]	Serov A., Kwak C., Appl. Catal. B,2010, 98(1/2), 1—9
[6]	http://www.platinum.matthey.com/prices/price-tables
[7]	Feng G., Kuang Y., Li Y., Sun X., Nano Res.,2015, 8(10), 3365—3371
[8]	Jeon T.Y., Watanabe M., Miyatake K., ACS Appl. Mater. Interfaces,2014, 6(21), 18445—18449
[9]	Wang J., Zhang Q., Li X., Xu D., Wang Z., Guo H., Zhang K., Nano Energy,2014, 6, 19—26
[10]	Hoang S., Gao P.X., Adv. Energy Mater.,2016, 6(23), 1600683
[11]	Lai M., Riley D.J., J. Colloid Interface Sci.,2018, 323(2), 203—212
[12]	Molares M. E.T., Brötz J., Buschmann V., Buschmann V., Dobrev D., Neumann R., Scholz R., Schuchert I.U., Trautmann C., Vetter J., Nucl. Instrum. Methods Phys. Res., Sect. B,2001, 185(1—4), 192—197
[13]	Graves J.E., Bowker M. E .A., Summer A., Greenwood A., Ponce de León C., Walsh F.C., Electrochem. Commun.,2018, 87, 58—62
[14]	Xu Q., Meng G., Han F., Prog. Mater. Sci.,2018, 95, 243—285
[15]	Geng X., Navarrete E., Liang W., Podlaha E.J., Mater. Lett.,2018, 211, 9—12
[16]	Matei E., Florica C., Costas A., Toimil-Molares M.E., Enculescu I., Beilstein J. Nanotechnol.,2015, 6, 444—450
[17]	Li J.C., Wu J.Z., Zhou C., Gong X., Acta Phys. Chim. Sin.,2013, 29(6), 1123—1144
[18]	Trasatti S., Petrii O.A., Pure Appl. Chem.,1991, 63(5), 711—734
[19]	Guo F., Cao D., Du M., Ye K., Wang G., Zhang W., Gao Y., Cheng K., J. Power Sources,2016, 307, 697—704
[20]	Louie M.W., Bell A.T., J. Am. Chem. Soc.,2013, 135(33), 12329—12337
[21]	Yeo B.S., Bell A.T., J. Phys. Chem. C,2012, 116(15), 8394—8400
[22]	Li T., Studies on the Conversion Materials for High-Capacity Cathode of Li-ion Batteries, Wuhan University, Wuhan, 2011
	(李婷. 锂离子电池高容量转换正极材料的研究, 武汉: 武汉大学, 2011)
[23]	Guo F., Li Y., Fan B., Liu Y., Lu L., Lei Y., ACS Appl. Mater. Interfaces,2018, 10(5) 4705—4714
[24]	Liu R., Ye K., Gao Y., Zhang W., Wang G., Cao D., Electrochim. Acta,2015, 186, 239—244

自支撑镍纳米线阵列电极的制备及电催化性能

Preparation and Electro-catalytic Property of Self-supported Nickel Nanowire Array Electrode^†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 24

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王广琦, 毕艺洋, 王嘉博, 石洪飞, 刘群, 张钰. 非贵金属三元复合Ni(PO₃)₂-Ni₂P/CdS NPs异质结的构建及可见光高效催化产氢性能[J]. 高等学校化学学报, 2022, 43(6): 20220050.
[2]	李晓辉, 魏爱佳, 穆金萍, 何蕊, 张利辉, 王军, 刘振法. 磷酸钐包覆对高电压镍锰酸锂正极材料电化学性能的影响[J]. 高等学校化学学报, 2022, 43(2): 20210546.
[3]	郭彪, 赵晨灿, 刘芯辛, 于洲, 周丽景, 袁宏明, 赵震. 表面水热碳层对磁性NiFe₂O₄八面体光催化活性的影响[J]. 高等学校化学学报, 2022, 43(11): 20220472.
[4]	侯从聪, 王惠颖, 李婷婷, 张志明, 常春蕊, 安立宝. N-CNTs/NiCo-LDH复合材料的制备及电化学性能[J]. 高等学校化学学报, 2022, 43(10): 20220351.
[5]	初明月, 李峰博, 高宁, 杨昕, 于婷婷, 马慧媛, 杨桂欣, 庞海军. 轮型多金属氧酸盐复合物膜的制备及在检测亚硝酸盐中的应用[J]. 高等学校化学学报, 2022, 43(1): 20210579.
[6]	樊晔, 韩慧慧, 方云, 冯瑞沁, 夏咏梅. 简易合成纳米多层级镍中空亚微球及其催化苯酚加氢的研究[J]. 高等学校化学学报, 2021, 42(6): 1801.
[7]	杨晓梅, 吴强, 郭茹, 叶凯波, 薛屏, 王晓中, 赖小勇 . 超薄骨架有序介孔CdS/NiS的制备及光催化产氢性能[J]. 高等学校化学学报, 2021, 42(5): 1581.
[8]	王弈艨, 刘凯, 王保国. 高镍三元正极材料的表面包覆策略[J]. 高等学校化学学报, 2021, 42(5): 1514.
[9]	张会双, 高延晓, 王秋娴, 李向南, 刘文凤, 杨书廷. CTAB辅助水热合成高镍三元材料LiNi_0.6Co_0.2Mn_0.2O₂及其高低温性能研究[J]. 高等学校化学学报, 2021, 42(3): 819.
[10]	黄岩, 张树鑫, 努丽燕娜, 王保峰, 杨军, 王久林. 用于镁硫电池的原位生长NiS的泡沫镍正极集流体[J]. 高等学校化学学报, 2021, 42(3): 794.
[11]	肖兆忠, 马智, 朴玲钰. 不同半导体体系中磷化镍光催化甲酸分解的助催化作用[J]. 高等学校化学学报, 2021, 42(12): 3692.
[12]	李肖乾, 张华, 路海健, 刘畅, 刘庆龙, 马夏禹, 方媛萍, 梁大鹏. 内部萃取电喷雾电离质谱对二氧化钛纳米线阵列光催化降解罗丹明B反应机理的研究[J]. 高等学校化学学报, 2020, 41(9): 2003.
[13]	赵国庆, 袁钊, 王连, 郭卓. 磷化镍/氮硫双掺杂石墨烯复合材料的制备及电催化析氢性能[J]. 高等学校化学学报, 2020, 41(7): 1575.
[14]	孙强强, 曹宝月, 周春生, 张国春, 王增林. 镍铜合金立方体纳米晶的脉冲电沉积及电催化析氢性能[J]. 高等学校化学学报, 2020, 41(6): 1287.
[15]	刘璐,伍含月,李静,佘岚. 铁镍合金催化剂的结构调控及对电化学析氧反应的催化性能[J]. 高等学校化学学报, 2020, 41(5): 1083.

自支撑镍纳米线阵列电极的制备及电催化性能

Preparation and Electro-catalytic Property of Self-supported Nickel Nanowire Array Electrode†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 24

相关文章 15

编辑推荐

Metrics

本文评价

Preparation and Electro-catalytic Property of Self-supported Nickel Nanowire Array Electrode^†