不同形貌普鲁士蓝纳米粒子的合成及光热性能

doi:10.7503/cjcu20170116

高等学校化学学报 ›› 2018, Vol. 39 ›› Issue (2): 359.doi: 10.7503/cjcu20170116

不同形貌普鲁士蓝纳米粒子的合成及光热性能

张书鹏¹, 程友星², 任磊², 文凯¹, 吕晓林², 叶社房²(), 周樨²()

1. 厦门大学材料学院材料科学与工程系, 厦门 361005
2. 厦门大学材料学院生物材料系, 生物医学工程福建省高校重点实验室,厦门市生物医学工程技术研究中心, 厦门 361005

收稿日期:2017-02-25 出版日期:2018-02-10 发布日期:2018-01-11
作者简介:联系人简介: 叶社房, 男, 博士, 副教授, 主要从事纳米生物效应研究. E-mail: yeshefang@xmu.edu.cn;周樨, 女, 博士, 副教授, 主要从事纳米生物材料研究. E-mail: xizhou@xmu.edu.cn
基金资助:
国家自然科学基金(批准号: 31271071, 31371012, U1505228)资助

Reparation and Photothermal Properties of Prussian Blue Nanoparticles with Different Morphologies^†

ZHANG Shupeng¹, CHENG Youxing², REN Lei², WEN Kai¹, LÜ Xiaolin², YE Shefang^2,^*(), ZHOU Xi^2,^*()

1. Department of Materials Science and Engineering, College of Materials,Xiamen University, Xiamen 361005, China
2. Key Laboratory of Biomedical Engineering of Fujian Province University/Research Center of Biomedical Engineering of Xiamen, Department of Biomaterials,College of Materials, Xiamen University, Xiamen 361005, China

Received:2017-02-25 Online:2018-02-10 Published:2018-01-11
Contact: YE Shefang,ZHOU Xi E-mail:yeshefang@xmu.edu.cn;xizhou@xmu.edu.cn
Supported by:
† Supported by the National Natural Science Foundation of China(Nos.31271071, 31371012, U1505228)

摘要/Abstract

摘要：

制备了立方体、直角立方体、球形、棒状、中空状、核壳状、梭形、多面体等8种不同形貌的普鲁士蓝纳米粒子, 利用扫描电子显微镜、透射电子显微镜、紫外-可见分光光度计等对纳米粒子进行了表征,考察了普鲁士蓝纳米粒子光热性能的影响因素. 结果表明, 普鲁士蓝纳米粒子的形貌与光热性能之间联系密切, 粒子形貌不同, 光热性能不同; 当外部实验条件一定时, 纳米粒子的形貌、大小、吸收横截面积、尖锐化程度及密实程度等对其光热性能有很大的影响; 当纳米粒子形貌一定时, 外部因素如激光器的选择、激光功率密度及纳米粒子的浓度等直接影响普鲁士蓝纳米粒子的光热性能; 在相同浓度下, 激光功率密度越大, 纳米粒子的升温效果越明显, 光热性能越好; 而激光功率密度不变时, 纳米粒子浓度越大, 其光热转换效率越高.

关键词: 普鲁士蓝纳米粒子, 形貌, 光热性能, 光热治疗

Abstract:

To clarify the factors that influence photothermal property, prussian blue nanoparticles(PB NPs) with different morphologies, including cube, rectangular cube, sphere, rod, hollow, core-shell, spindle and polyhedron, were synthesized and characterized by the scanning electron microscopy, X-ray diffraction and UV-Vis spectrophotometry. The results show that the morphologies of PB NPs were closely related to their photothermal property. And several factors, such as particle size, morphology, structure and the absorption cross-sectional area of particle, could make a huge difference in photothermal property under the same external experiment conditions. In addition, the experimental conditions, such as laser source, laser power density and the concentration of materials, could also play critical roles in photothermal property of PB NPs. Importantly, at the same concentration, the laser power density greatly affected the photothermal property of PB NPs. On the other hand, at the same laser power density, the higher concentration of PB NPs resulted in a better performance of photothermal property.

Key words: Prussian blue nanoparticles, Morphology, Photothermal property, Photothermal therapy

中图分类号:

O644

TrendMD:

张书鹏, 程友星, 任磊, 文凯, 吕晓林, 叶社房, 周樨. 不同形貌普鲁士蓝纳米粒子的合成及光热性能. 高等学校化学学报, 2018, 39(2): 359.

ZHANG Shupeng, CHENG Youxing, REN Lei, WEN Kai, LÜ Xiaolin, YE Shefang, ZHOU Xi. Reparation and Photothermal Properties of Prussian Blue Nanoparticles with Different Morphologies^†. Chem. J. Chinese Universities, 2018, 39(2): 359.

图/表 7

Fig.1 SEM(A—D, G, H) and TEM(E, F) images of PB nanoparticles(NPs) with different morphologies(A) Cube; (B) rectangular cube; (C) sphere; (D) rod; (E) core-shell; (F) hollow; (G) spindle; (H) polyhedron.

Fig.2 X-ray powder diffraction patterns of PB NPs with different morphologies

Fig.3 UV-Vis spectra of PB NPs with different morphologies(A) Before normalization; (B)after normalization. a. Polyhedron; b. spindle; c. hollow;d. rectangular cube; e. sphere; f. rod; g. cube; h. core-shere.

Fig.4 Temperature-rising curves of PB NPs under vary conditions(A) Different semiconductor excitation light source; (B)different laser power density; (C) different concentrations of PB NPs.

Table 1 Size, volume, absorption value and molar extinction coefficient of different PB NPs

Morphology	Particle size/nm	10¹⁵ Volume/cm³	10^-13ε_PB	A	10^-13ε
Cube	100(side length)	1	5.418A	0.3475	1.8
Rectangular cube	100	1	5.418A	0.4747	2.57
Sphere	100(diameter)	0.52	2.8A	0.1696	0.47
Rod	3000/200/10(long/wide/high)	6	32.5A	0.3083	10.02
Core-shell	200(length)	8	43.3A	0.5709	24.72
Hollow	100(length)	0.03	0.1A	0.0719	0.01
Spindle	500(long axis)	5.45	29.5A	0.1503	4.43
Polyhedron	250(hexagon length)	40.6	219.7A	0.4350	95.57

Fig.5 Rising curve of vary morphology at the same concentration(A), thermal infrared image at different time point(B) and absorption cross-sectional area of particle(C)a. H2O; b. cube; c. polyhedron; d. hollow; e. spindle; f. rectangular cube; g. sphere; h. rod; i. core-shell.

Table 2 Specific value of PB NPs with different morphologies

Sample	A₈₀₈	ΔT_max/℃	1 $0 - A 808$	1-1 $0 - A 808$	η
Cube	0.93	22.70	0.12	0.88	25.8/K-1.14
Rectangular cube	0.53	16.90	0.29	0.71	23.8/K-1.41
Sphere	0.92	10.30	0.12	0.88	11.7/K-1.14
Rod	0.94	19.50	0.11	0.89	21.9/K-1.12
Core-shell	0.95	5.40	0.11	0.89	6.07/K-1.12
Hollow	0.82	5.30	0.15	0.85	6.2/K-1.25
Spindle	0.52	5.60	0.30	0.70	8/K-1.43
Polyhedron	0.96	16.50	0.11	0.89	18.54/K-1.12

Table 2 Specific value of PB NPs with different morphologies

Sample	A₈₀₈	ΔT_max/℃	1 $0 - A 808$	1-1 $0 - A 808$	η
Cube	0.93	22.70	0.12	0.88	25.8/K-1.14
Rectangular cube	0.53	16.90	0.29	0.71	23.8/K-1.41
Sphere	0.92	10.30	0.12	0.88	11.7/K-1.14
Rod	0.94	19.50	0.11	0.89	21.9/K-1.12
Core-shell	0.95	5.40	0.11	0.89	6.07/K-1.12
Hollow	0.82	5.30	0.15	0.85	6.2/K-1.25
Spindle	0.52	5.60	0.30	0.70	8/K-1.43
Polyhedron	0.96	16.50	0.11	0.89	18.54/K-1.12

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不同形貌普鲁士蓝纳米粒子的合成及光热性能

Reparation and Photothermal Properties of Prussian Blue Nanoparticles with Different Morphologies^†

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不同形貌普鲁士蓝纳米粒子的合成及光热性能

Reparation and Photothermal Properties of Prussian Blue Nanoparticles with Different Morphologies†

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Reparation and Photothermal Properties of Prussian Blue Nanoparticles with Different Morphologies^†