二维胶体晶体异质结构的制备及传感性

doi:10.7503/cjcu20150274

高等学校化学学报 ›› 2015, Vol. 36 ›› Issue (8): 1612.doi: 10.7503/cjcu20150274

二维胶体晶体异质结构的制备及传感性

齐丰莲, 薛敏(), 薛飞, 孟子晖(), 邱丽莉, 徐志斌, 芦薇

北京理工大学化工与环境学院, 北京 100081

收稿日期:2015-04-08 出版日期:2015-08-10 发布日期:2015-06-12
作者简介:联系人简介: 薛敏, 女, 博士, 讲师, 主要从事光子晶体和色谱分析研究. E-mail:minxue@bit.edu.cn;孟子晖, 男, 博士, 教授, 博士生导师, 主要从事光子晶体研究. E-mail:m_zihui@yahoo.com
基金资助:
国家自然科学基金(批准号: 21375009)资助

Preparation and Chemical Sense Character of Two-dimensional Colloidal Crystal Heterostructures^†

QI Fenglian, XUE Min^*(), XUE Fei, MENG Zihui^*(), QIU Lili, XU Zhibin, LU Wei

School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China

Received:2015-04-08 Online:2015-08-10 Published:2015-06-12
Contact: XUE Min,MENG Zihui E-mail:minxue@bit.edu.cn;m_zihui@yahoo.com
Supported by:
† Supported by the National Natural Science Foundation of China(No.21375009)

摘要/Abstract

摘要：

制备具有不同粒径和折射率的聚苯乙烯(PS)和聚甲基丙烯酸甲酯(PMMA)微球, 采用多次尖端导流法制备多重二维胶体晶体异质结构(2D-CCHs)阵列, 在2D-CCHs阵列的间隙处填充丙烯酸类凝胶, 再将PS或PMMA模板微球去掉, 得到传质速度更快的2D-CCHs反蛋白石凝胶. 经扫描电子显微镜证实, 所制备的异质结构胶体晶体均为二维结构, 且排列较为规整. 德拜衍射、反射光谱和结构色分析结果表明, 2D-CCHs的光学性质主要是各单层二维胶体晶体阵列独立衍射的叠加. 随着pH值由7降低至3, 双层2D-CCHs反蛋白石凝胶的德拜衍射环直径均减小了约80 nm, 表明2D-CCHs反蛋白石凝胶可应用于化学传感领域.

关键词: 胶体晶体, 异质结构, 尖端导流, 聚苯乙烯, 聚甲基丙烯酸甲酯

Abstract:

Polystyrene(PS) and poly(methyl methacrylate)(PMMA) suspensions with different particle sizes and refractive index were prepared. A successive air/water interface self-assembly method was developed to fabricate two-dimensional colloidal crystal heterostructures(2D-CCHs) array. Furthermore, 2-hydroxyethyl methacrylate-acrylic acid(HEMA-AA) 2D-CCHs inverse opals with high mass transfer efficiencies were obtained after removing the opal templates. The prepared heterostructures are highly ordered two-dimensional structures proved by scanning electron microscopy images(SEM). Debye diffraction rings, reflectance spectra and structural colors suggested that the optical properties of 2D-CCHs are attributed to overlay of the individual diffraction of single 2D colloidal crystal. With the pH value decreased from 7 to 3, Debye diffraction rings’ diameters of double-layers 2D-CCHs inverse opals both shrank nearly 80 nm. The response of 2D-CCHs to pH indicates their preliminary application in chemical sensors.

Key words: Colloidal crystal, Heterostructure, Air/water interface self-assembly method, Polystyrene, Poly(methyl methacrylate)

中图分类号:

O631
O613.7

TrendMD:

齐丰莲, 薛敏, 薛飞, 孟子晖, 邱丽莉, 徐志斌, 芦薇. 二维胶体晶体异质结构的制备及传感性. 高等学校化学学报, 2015, 36(8): 1612.

QI Fenglian, XUE Min, XUE Fei, MENG Zihui, QIU Lili, XU Zhibin, LU Wei. Preparation and Chemical Sense Character of Two-dimensional Colloidal Crystal Heterostructures^†. Chem. J. Chinese Universities, 2015, 36(8): 1612.

图/表 7

Scheme 1 The preparation of 2D colloidal crystal heterostructures(2D-CCHs) inverse opals

Fig.1 SEM images of 2D colloidal crystal arrays with different monodisperse particles(A) PS, size: 590 nm; (B) PS+NaCl, size: 640 nm; (C) PMMA, size: 710 nm.

Fig.2 Top-view SEM(A—C) and cross-sectional SEM(D—F) of 2D-CCHs with 590 nm PS(A,D), 590 nm PS-640 nm PS(B,E) and 590 nm PS-640 nm PS-710 nm PMMA(C,F)

Fig.3 Debye diffraction rings(A—C) and the structure color(D—F) of 2D-CCHS with 590 nm PS(A, D), 590 nm PS-640 nm PS(B, E) and 590 nm PS-640 nm PS-710 nm PMMA(C, F)

Fig.4 Change of Debye diffraction rings(A) and structure color(B) of double-layers 2D-CCHs inverse opals response to pH

Fig.5 Top-view SEM(A—C) and cross-sectional view SEM(D—F) of single-layer(A, D), double-layers(B, E) and triple-layers(C, F) 2D-CCHs inverse opals

Fig.6 Reflectance spectrum of triple-layers 2D-CCHs inverse opals

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二维胶体晶体异质结构的制备及传感性

Preparation and Chemical Sense Character of Two-dimensional Colloidal Crystal Heterostructures^†

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二维胶体晶体异质结构的制备及传感性

Preparation and Chemical Sense Character of Two-dimensional Colloidal Crystal Heterostructures†

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Preparation and Chemical Sense Character of Two-dimensional Colloidal Crystal Heterostructures^†