高等学校化学学报 ›› 2013, Vol. 34 ›› Issue (6): 1318.doi: 10.7503/cjcu20121156

• 研究论文: 无机化学 • 上一篇    下一篇

[Eu(Bipy)2]Cl3和[Tb(Bipy)2]Cl3在有机功能化剥层水滑石表面上的组装及光致发光性质

赵秀巧, 王会, 董丽君, 徐庆红   

  1. 北京化工大学化工资源有效利用国家重点实验室, 北京 100029
  • 收稿日期:2012-12-21 出版日期:2013-06-10 发布日期:2013-04-01
  • 通讯作者: 徐庆红,男,博士,副教授,从事无机功能材料的合成及性质研究.E-mail:xuqh@mail.buct.edu.cn E-mail:xuqh@mail.buct.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 50602004)资助.

Assembly of Rare-earth Complex [Eu(Bipy)2]Cl3 and [Tb(Bipy)2]Cl3 on Surface Modified Exfoliated LDHs and Photoluminescent Properties of the Assemblies

ZHAO Xiu-Qiao, WANG Hui, DONG Li-Jun, XU Qing-Hong   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2012-12-21 Online:2013-06-10 Published:2013-04-01

摘要:

以乙酰基丙氨基三乙氧基硅烷对剥层镁铝水滑石进行了表面硅烷化修饰, 得到了表面硅烷化修饰的剥层水滑石复合材料. 然后在该复合材料表面进行了[Eu(Bipy)2]3+和[Tb(Bipy)2]3+分子组装, 得到了剥层水滑石复合稀土发光体. 组装体的紫外激发发射光谱表明, 稀土配合物被组装到经硅烷化试剂修饰的剥层水滑石表面后, 其电偶极跃迁较原配合物有很大提高, 热稳定性也有提高.从主客体材料相互作用角度对稀土配合物电偶极跃迁的提高进行了解释.

关键词: 稀土配合物, 激发发射光谱, 剥层水滑石, 硅烷化修饰

Abstract:

[Eu(Bipy)2]Cl3 and [Tb(Bipy)2]Cl3 are assembled on surface of exfoliated Mg2Al-NO3-LDH modified with N——acetamide by covalent bonding and photophysical properties of the assembly were studied. Emission spectra show that the fluorescence intensities of the rare earth complexes are increased on the surface of exfoliated Mg2Al-NO3-LDH greatly. The fluorescence intensities of EM-Mg2Al-NO3-LDH/[Eu(Bipy)2]3+ and EM-Mg2Al-NO3-LDH/[Tb(Bipy)2]3+ are 43.5 and 53.7 times of the pure compelex. XPS and UV-Vis studies show that the increase is illuminated from the interactions between the host and guests, and the affections from host’s structure to the luminance of guests were studied carefully.

Key words: Rare-earth complex, Excitation and emission spectra, Exfoliated Mg2Al-NO3-LDH, Silane modification

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