The Effect of Tetraethylammonium Ion on the Surface Activities and Micelle Formation of Anionic Surfactants and Their Mixtures

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (12): 1838.

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The Effect of Tetraethylammonium Ion on the Surface Activities and Micelle Formation of Anionic Surfactants and Their Mixtures

ZHANG Lan-Hui, CAI Zhou-Fu, DING Hui-Jun, ZHAO Guo-Xi

Department of Chemistry, Peking University, Beijing, 100871

Received:1994-02-21 Revised:1994-05-22 Online:1994-12-24 Published:1994-12-24

Abstract

Abstract: Results are presented of the effects of tetraethylammonium ion on the surface activities and micelle formation of anionic surfactants and their mixtures. Tetraethylammonium ion behaves as an inorganic ion when its concentration is low, but is obviously participates in the adsorption and micellization when its concentration gets higher. It seems that a hydrocarbon chain was introduced onto the hydrophobic chain of surfactants. As a result, the surfactants act higher surface acitivties and the mutual phobicity between the fluorocarbon and hydrocarbon surfactants is reduced.

Key words: Surfactant, Tetraethylammonium dodecylsulfate, Tetraethylammonium perfluorooctyl sulfonate, Tetraethylammonium bromide

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ZHANG Lan-Hui, CAI Zhou-Fu, DING Hui-Jun, ZHAO Guo-Xi. The Effect of Tetraethylammonium Ion on the Surface Activities and Micelle Formation of Anionic Surfactants and Their Mixtures[J]. Chem. J. Chinese Universities, 1994, 15(12): 1838.

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The Effect of Tetraethylammonium Ion on the Surface Activities and Micelle Formation of Anionic Surfactants and Their Mixtures

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