Synthesis,Characterization and Crystal Structure Studies on a Mixed Ligand Complex of Aquatris(3-phenyl-4-benzoyl-5-isoxazolone)(Ethanol) Europium Monohydrate[Eu(PBI)3(C2H5OH)(H2O)]·H2O

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (2): 172.

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Synthesis,Characterization and Crystal Structure Studies on a Mixed Ligand Complex of Aquatris(3-phenyl-4-benzoyl-5-isoxazolone)(Ethanol) Europium Monohydrate[Eu(PBI)₃(C₂H₅OH)(H₂O)]·H₂O

WEI Zhao-Jie¹, LI Biao-Guo¹, HUANG Chun-Hui¹, S. Umetani², M. Matsui²

1. State Key Laboratory of Rare Earth Material Chemistry and Applications, Peking University, Beijing, 100871;
2. Institute for Chemical Research, Kyoto University, Kyoto 611, Japan

Received:1994-07-28 Revised:1994-10-22 Online:1995-02-24 Published:1995-02-24

Abstract

Abstract: The[Eu(PBI)₃(C₂H₅OH)(H₂O)]·H₂O was systhesized by reacting Eu₂O₃with highly acidic β-diketone 3-phenyl-4-benzoyl-5-isoxazolone(HPBI) in C₂H₅OH under heating.The X-ray single crystal structure analysis shows that the crystal is monoclinic with space group P2₁/a and the unit cell parameters are as follows:a=1.5586(9) nm,b=2.1297(7) nm,c=1.604(1) nm,β=117.97(5)°,V=4.703(9) nm³,Z=4.The central ion Eu³⁺is eight coordinated by six oxygen atoms from three β-diketone,one from water and one from C₂H₅OH molecule.The coordination polyhedron takes bicapped triangular prism arrangement.The Eu-Oaverage bond length is 0.2391(4) nm.The average distance of O-Owithin a β-diketone is 0.2808 nm which is larger than those for other β-diketones.

Key words: Europuim complex, Crystal structure, Isoxazolone

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WEI Zhao-Jie, LI Biao-Guo, HUANG Chun-Hui, S. Umetani, M. Matsui. Synthesis,Characterization and Crystal Structure Studies on a Mixed Ligand Complex of Aquatris(3-phenyl-4-benzoyl-5-isoxazolone)(Ethanol) Europium Monohydrate[Eu(PBI)₃(C₂H₅OH)(H₂O)]·H₂O[J]. Chem. J. Chinese Universities, 1995, 16(2): 172.

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Synthesis,Characterization and Crystal Structure Studies on a Mixed Ligand Complex of Aquatris(3-phenyl-4-benzoyl-5-isoxazolone)(Ethanol) Europium Monohydrate[Eu(PBI)₃(C₂H₅OH)(H₂O)]·H₂O

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