Studies on the Inclusion Property of 5,11,17,23-Tetra-tert-butyl-25,26, 27,28-tetrakis[3-(methoxycarbonyl)benzyloxy]calixarene

Abstract

Abstract: The synthesis of a novel host blocked in the cone conformation and bearing m-methoxycarbonylbenzyl groups at the lower rim is described. X-ray crystal structure analysis revealed that action of one molecule of compound upon one molecule of CH₃CN or one molecule of CH₃NO₂, forms an intramolecular inclusion complex, respectively, by CH₃-π interactions. The complex of L with tetrabutyl ammonium bromide(TBAB), L·TBAB, was obtained. The results of DTA-TG and XRD analysis of L·TBAB can also be considered as an intramolecular inclusion complex.

Key words: Calixarene, Crystal structure, Quaternary ammonium cation, Inclusion complex

CLC Number:

O641.3

TrendMD:

ZHOU Zhi-Xian, SHI Ya-Lin, DU Chen-Xia, XING Yan-Jun, WU Yang-Jie . Studies on the Inclusion Property of 5,11,17,23-Tetra-tert-butyl-25,26, 27,28-tetrakis[3-(methoxycarbonyl)benzyloxy]calixarene[J]. Chem. J. Chinese Universities, 2002, 23(12): 2281.

References

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