Synthesis and Structure of Complex E(η5-Me3SiC5H3)2[Fe(CO)]2(μ-CO)2

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (7): 1065.

• Articles • Previous Articles Next Articles

Synthesis and Structure of Complex E(η⁵-Me₃SiC₅H₃)₂[Fe(CO)]₂(μ-CO)₂

XU Shan-Sheng¹, XIE Wen-Hua¹, ZHOU Xiu-Zhong¹, WANG Jin-Ling², CHEN Hong-Li², GUO Hong-sheng², MIAO Fang-Ming²

1. Department of Chemistry, Nankai University, Tianjin 300071;
2. Institute of Chemical Crystallography, Tianjin Normal University

Received:1995-08-07 Online:1996-07-24 Published:1996-07-24

Abstract

Abstract: Complexes E(η⁵-Me₃SiC₅H₃)₂ [Fe(CO)]₂(μ-CO)₂[E=Me₂Si(1),Me₂SiOSiMe₂(2)] were obtained by reaction of bridged compounds E(Me₃SiC₅H₄)₂[E=Me₂Si(Ⅰ),Me₂SiOSiMe₂(Ⅱ)]with Fe(CO)₅ in refluxing xylene.Compounds 1,2 were revealed to be cis-isomers by ¹H NMRspectra and X-ray diffraction analysis.Extensive desilylation was observed.Crystals of 1 and 2 are monoclinic, belonging to space-group P2₁/m.1:a=0.7359(3)nm,b=1.9409(1)nm,c=0.9383(5)nm,β=99.71(4)°,V=1.32010(1) nm³,Z= 2,D_c=1.394 g/mL;2:α=0.6743(5)nm,b=2.2635(5)nm,c=1.0802(1) nm,β= 108.1(2)°,V=1.5668(2)nm³ Z=2,D_c=1.493 g/mL.

Key words: Bridged biscyclopentadiene, Fe─Fe complex, Stereo configuration, Structure

TrendMD:

XU Shan-Sheng, XIE Wen-Hua, ZHOU Xiu-Zhong, WANG Jin-Ling, CHEN Hong-Li, GUO Hong-sheng, MIAO Fang-Ming. Synthesis and Structure of Complex E(η⁵-Me₃SiC₅H₃)₂[Fe(CO)]₂(μ-CO)₂[J]. Chem. J. Chinese Universities, 1996, 17(7): 1065.

[1]	WANG Sicong, PANG Beibei, LIU Xiaokang, DING Tao, YAO Tao. Application of XAFS Technique in Single-atom Electrocatalysis [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220487.
[2]	JIANG Bowen, CHEN Jingxuan, CHENG Yonghua, SANG Wei, KOU Zongkui. Recent Progress of Single-atom Materials in Electrochemical Biosensing [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220334.
[3]	LI Lin, QI Fenglian, QIU Lili, MENG Zihui. Dynamic Amorphous Photonic Structure Patterns Assembled by Hexagonal Magnetic Nanosheets [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220123.
[4]	JIA Yanggang, SHAO Xia, CHENG Jie, WANG Pengpeng, MAO Aiqin. Preparation and Lithium Storage Performance of Pseudocapacitance-controlled Perovskite High-entropy Oxide La（Co_0.2Cr_0.2Fe_0.2Mn_0.2Ni_0.2）O₃ Anode Materials [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220157.
[5]	WU Yushuai, SHANG Yingxu, JIANG Qiao, DING Baoquan. Research Progress of Controllable Self-assembled DNA Origami Structure as Drug Carrier [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220179.
[6]	YANG Dan, LIU Xu, DAI Yihu, ZHU Yan, YANG Yanhui. Research Progress in Electrocatalytic CO₂ Reduction Reaction over Gold Clusters [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220198.
[7]	ZHAO Yingzhe, ZHANG Jianling. Applications of Metal-organic Framework-based Material in Carbon Dioxide Photocatalytic Conversion [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220223.
[8]	CHEN Weiqin, LYU Jiamin, YU Shen, LIU Zhan, LI Xiaoyun, CHEN Lihua, SU Baolian. Preparation of Organic Hybrid Mesoporous Beta Zeolite for Alkylation of Mesitylene with Benzyl Alcohol [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220086.
[9]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[10]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[11]	ZHU Kai, LI Jie, WU Xiaoyi, HU Weiwei, WU Dongmei, YU Chengxiao, GE Zhiwei, YE Xingqian, CHEN Shiguo. Combined PGC-Triple-Tof-MS Enables the Separation， Identification of Sugar Beet Pectin Derived Oligomers [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220023.
[12]	XIA Tian, WAN Jiawei, YU Ranbo. Progress of the Structure-property Correlation of Heteroatomic Coordination Structured Carbon-based Single-atom Electrocatalysts [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220162.
[13]	GU Yu, XI Baojuan, LI Jiangxiao, XIONG Shenglin. Structure Regulation of Single-atom Catalysts in Oxygen Reduction Reactions [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220036.
[14]	XU Siran, YIN Hengbo, XUE Dongping, XIA Huicong, ZHAO Shuyan, YAN Wenfu, MU Shichun, ZHANG Jianan. Atomically Dispersed Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction Reaction [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220028.
[15]	GUO Jinchang, LIU Fanglin. Planar Pentacoordinate Silicon and Germanium in XBe₅H₆（X=Si， Ge） Clusters [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210807.

Synthesis and Structure of Complex E(η⁵-Me₃SiC₅H₃)₂[Fe(CO)]₂(μ-CO)₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments