Synthesis, Characterization and Catalytic Performance of Copper(Ⅱ)-8-quinolinol Functionalized SBA-15

Chem. J. Chinese Universities

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Synthesis, Characterization and Catalytic Performance of Copper(Ⅱ)-8-quinolinol Functionalized SBA-15

WANG Hong-Su, HUANG Jia-Hui, XU Chen, XU Ling, SONG Ke, XU Hai-Yan, WANG Zhu-Qian, KAN Qiu-Bin*

College of Chemistry, Jilin University, Changchun 130021, China

Received:2006-11-04 Revised:1900-01-01 Online:2007-07-10 Published:2007-07-10
Contact: KAN Qiu-Bin

Abstract

Abstract: Firstly, copper(Ⅱ)-8-quinolinol ligands were introduced into the channels of 3-aminopropyl functionalized mesoporous SBA-15(denoted as APS-SBA-15). Then, the obtained copper(Ⅱ)-8-quinolinol functionalized SBA-15 materials[named as Cu(Ⅱ)-Q-APS-SBA-15] were tested as the catalysts for phenol hydroxylation by using H₂O₂(30%, mass fraction) as an oxidant. The reaction results indicate that Cu(Ⅱ)-Q-APS-SBA-15 was an excellent catalyst for this reaction, and over it a high conversion of phenol and a high selectivity to diphenol could be obtained.

Key words: SBA-15, Copper(Ⅱ)-8-quinolinol, Phenol hydroxylation, Catalytic performance

CLC Number:

O643.3

TrendMD:

WANG Hong-Su, HUANG Jia-Hui, XU Chen, XU Ling, SONG Ke, XU Hai-Yan, WANG Zhu-Qian, KAN Qiu-Bin*. Synthesis, Characterization and Catalytic Performance of Copper(Ⅱ)-8-quinolinol Functionalized SBA-15[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Characterization and Catalytic Performance of Copper(Ⅱ)-8-quinolinol Functionalized SBA-15

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