Preparation of Cyclodextrin-based Mesoporous Carbon and Its Catalytic Performance†

doi:10.7503/cjcu20160216

Abstract

Abstract:

Mesoporous carbons with tailored pore size were prepared by technologies of ammonium perchlorate oxidation and hard template with hydroxypropyl-β-cyclodextrin as the structure-director and tetraethoxysilane as the silica precursor. The structures and surface chemistry properties of these carbon materials were characterized by N₂ adsorption, TEM, XRD and FTIR measurements. Their catalytic performances were investigated through the reduction of nitroaromatic using hydrazine hydrate as the reducing agent. The results showed that mesoporous carbon materials prepared using hydroxypropyl-β-cyclodextrin-based silicas as inorganic templates synthesized by ammonium perchlorate oxidation have worm-like pore structure and higher catalytic activity, especially mesoporous carbon prepared through oxidation under room temperature, the yield of p-methylaniline is 88.48% in the presence of the catalyst, and it still keeps higher activity after being reused for 4 times through a simple filtration, washed with ethanol and dried. Higher surface area and pore volume, and the presence of abundant surface oxygen-containing functional groups, which originates from the special preparation process of carbon material, are likely responsible for the high catalytic property of these mesoporous carbon materials.

Key words: Hydroxypropyl-β-cyclodextrin, Mesoporous carbon, Ammonium perchlorate oxidation, Nitroaromatic, Catalytic performance

CLC Number:

O643.36

TrendMD:

WANG Huichun, WANG Fachun, LI Baolin. Preparation of Cyclodextrin-based Mesoporous Carbon and Its Catalytic Performance^†[J]. Chem. J. Chinese Universities, 2016, 37(11): 2076.

Figures/Tables 13

References 33

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Sample	S_BET/(m²·g^-1)	S_mic/(m²·g^-1)	V_t/(cm³·g^-1)	V_mic/(cm³·g^-1)	D_BJH/nm
MS-cal	171	2	0.12	0.0005	3.5
MS-rt	848	5	0.33	0.0050	3.4
MS-60	849	3	0.58	0.0050	3.5
MS-80	782	13	1.11	0.0070	4.8
MS-100	594	39	1.32	0.0170	6.0

Sample	S_BET/(m²·g^-1)	S_mic/(m²·g^-1)	V_t/(cm³·g^-1)	V_mic/(cm³·g^-1)	D_BJH/nm
MS-cal	171	2	0.12	0.0005	3.5
MS-rt	848	5	0.33	0.0050	3.4
MS-60	849	3	0.58	0.0050	3.5
MS-80	782	13	1.11	0.0070	4.8
MS-100	594	39	1.32	0.0170	6.0

Sample	S_BET/(m²·g^-1)	S_mic/(m²·g^-1)	V_t/(cm³·g^-1)	V_mic/(cm³·g^-1)	V_mes/(cm³·g^-1)	D_BJH/nm
MC-cal	562	376	0.38	0.20	0.18	3.9
MC-rt	1240		1.33		1.33	3.9
MC-60	1430		1.52		1.52	3.3
MC-80	1407		1.58		1.58	3.3
MC-100	1222	154	1.74	0.07	1.67	3.7

Sample	S_BET/(m²·g^-1)	S_mic/(m²·g^-1)	V_t/(cm³·g^-1)	V_mic/(cm³·g^-1)	V_mes/(cm³·g^-1)	D_BJH/nm
MC-cal	562	376	0.38	0.20	0.18	3.9
MC-rt	1240		1.33		1.33	3.9
MC-60	1430		1.52		1.52	3.3
MC-80	1407		1.58		1.58	3.3
MC-100	1222	154	1.74	0.07	1.67	3.7

Sample	Time^b/min	Yield^c(%)	Sample	Time^b/min	Yield^c(%)
Without any catalysts	720	0	MC-60	240	85.23±0.11
Activated carbon	720	0	MC-80	300	83.72±0.21
MC-cal	480	71.68±0.12	MC-100	180	82.95±0.24
MC-rt	30	88.48±0.17