Structural Features and Formation Kinetics of CnDm-Cluster Ions

Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (2): 294.

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Structural Features and Formation Kinetics of C_nD_m^-Cluster Ions

ZHOU Yi-Nan², CHEN Hong¹, TANG Zi-Chao¹, ZHANG Qiang¹, HUANG Rong-Bin¹, ZHENG Lan-Sun¹

1. State Key Lab. for Physical Chemistry of the Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen, 61005;
2. Department of Basic Courses, XinXiang Medical College, XinXiang, 453003

Received:1998-03-16 Online:1999-02-24 Published:1999-02-24

Abstract

Abstract: By laser ablating of anthracene-d₁₀sample, various C_nD_m^-and C_n^-cluster anions were generated. The distribution suggests that the structural configuration and stability of the clusters varied with the number of deuteriuMAtoms and the parity of number of carbons. With growing size of the clusters, their structural configuration changes from chain to monocycle, and further to polycycle. The analysis of the distribution also reveals the formation kinetics of the clusters.

Key words: Carbon cluster, DeuteriuMAtom, Structure, Formation kinetics

CLC Number:

O641

TrendMD:

ZHOU Yi-Nan, CHEN Hong, TANG Zi-Chao, ZHANG Qiang, HUANG Rong-Bin, ZHENG Lan-Sun. Structural Features and Formation Kinetics of C_nD_m^-Cluster Ions[J]. Chem. J. Chinese Universities, 1999, 20(2): 294.

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Structural Features and Formation Kinetics of C_nD_m^-Cluster Ions

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