Synthesis of N-Aroyl-N'-arylselenoureas under Phase Transfer Catalysis Conditions and Its Crystal Structure

Chem. J. Chinese Universities

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Synthesis of N-Aroyl-N'-arylselenoureas under Phase Transfer Catalysis Conditions and Its Crystal Structure

WEI Tai-Bao, WANG Hai, LIN Qi, ZHANG You-Ming

College of Chemistry and Chemical Engineering, Gansu Province Key Laboratory of Polymer Materials, Northwest Normal University, Lanzhou 730070, China

Received:2005-08-02 Revised:1900-01-01 Online:2006-09-10 Published:2006-09-10
Contact: ZHANG You-Ming

Abstract

Abstract: A series of N-aroyl-N'-arylselenoureas(2a—2l) were synthesized at room temperature under phase transfer catalysis conditions by using polyethylene glycol-400 as the catalyst and the structure of compound 2a was confirmed by X-ray crystallographic analysis. In the crystal, compound 2a was assembled to a three-dimensional supramolecular structure by intermolecular hydrogen bonds. The crystal belongs to the monoclinic crystal system, P2₁/c space group with a=0.607 1(8) nm, b=2.605(3) nm, c=0.918 9(12) nm, β=92.43(2)°, V=1.452(3) nm³, Z=4, D_c=1.525 g/cm³; F(000)=672, μ=2.589 mm^-1.

Key words: Aroylselenourea, Aroylisoselenocyanate, Phase transfer catalysis, Crystal structure, Supramolecule

CLC Number:

O625

TrendMD:

WEI Tai-Bao, WANG Hai, LIN Qi, ZHANG You-Ming. Synthesis of N-Aroyl-N'-arylselenoureas under Phase Transfer Catalysis Conditions and Its Crystal Structure[J]. Chem. J. Chinese Universities, doi: .

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Synthesis of N-Aroyl-N'-arylselenoureas under Phase Transfer Catalysis Conditions and Its Crystal Structure

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