Hydrothermal Synthesis and Characteristic of [C6N2H18]2[Mo5O15(HPO4)2]·H2O

Abstract

Abstract: C₆N₂H18]₂[Mo₅O15(HPO₄)₂]·H₂O has been obtained by using hydrothermal synthesis, and the results of X-ray single crystal diffraction show that the compound crystalliized in space group {P3(2)₂1} of trigonal system with a=1.123 1(1) nm, c=2.280 2(5) nm, V=2.491 1(7) nm³, D_x=2^835 {Mg/m³}, Z=6 and R=0.022 7, wR=0.067 5. The crystal structure of [C₆N₂H18]₂[Mo₅O15(HPO₄)₂]·H₂O is composed of two protoned tertramethyldiamine, [C₆N₂H18] 4+₂, [Mo₅O15(HPO₄)₂] 4- and one molecule water. In the anion H₂Mo₅P₂O 4-23, five octahedral MoO₆ are connected by sharing-angle to form a pentagon and three oxygen atoms of two PO₄ tetrahedral is connected to five Mo atoms. Five octahedral MoO₆ and two PO₄ tetrahedral are connected to form this anion like flying saucer.

Key words: Crystal, Hydrothermal synthesis, Structure

CLC Number:

O614.61

TrendMD:

LI Ya-Feng, CUI Wei, ZHU Guang-Shan, QIU Shi-Lun, FANG Qian-Rong, WANG Chun-Lei . Hydrothermal Synthesis and Characteristic of [C₆N₂H₁₈]₂[Mo₅O₁₅(HPO₄)₂]·H₂O[J]. Chem. J. Chinese Universities, 2003, 24(3): 394.

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Hydrothermal Synthesis and Characteristic of [C₆N₂H₁₈]₂[Mo₅O₁₅(HPO₄)₂]·H₂O

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