Chem. J. Chinese Universities ›› 2014, Vol. 35 ›› Issue (8): 1620.doi: 10.7503/cjcu20140302
• Articles: Inorganic Chemistry • Previous Articles Next Articles
CHI Yuxian, QIU Juqing, LI Shumei, YANG Yanhong, JIN Jing, NIU Shuyun*()
Received:
2014-04-02
Online:
2014-08-10
Published:
2019-08-01
Contact:
NIU Shuyun
E-mail:syniu@sohu.com
Supported by:
CLC Number:
TrendMD:
CHI Yuxian, QIU Juqing, LI Shumei, YANG Yanhong, JIN Jing, NIU Shuyun. Syntheses, Structures and Photophysical Properties of a Series of Sm3+ Coordination Complexes†[J]. Chem. J. Chinese Universities, 2014, 35(8): 1620.
Complex | 1 | 2 | 3 | 4 |
---|---|---|---|---|
Empirical formula | C18H14N2 | C38H31N2O11SmZn | C42H34N6O29Sm2 | C6H12NO9Sm |
Formula mass | 682.03 | 907.37 | 1387.45 | 392.52 |
Crystal system | Monoclinic | Triclinic | Triclinic | Orthorhombic |
Space group | P21/c | P | P | Pbca |
a/nm | 0.99546(10) | 1.0887(2) | 0.9410(3) | 0.81136(13) |
b/nm | 2.2139(2) | 1.3527(3) | 1.5371(5) | 1.3133(2) |
c/nm | 0.97660(10) | 1.3910(3) | 1.8882(7) | 2.0779(3) |
α/(°) | 90 | 70.219(2) | 75.188(4) | 90 |
β/(°) | 102.6150(10) | 84.491(2) | 80.863(4) | 90 |
γ/(°) | 90 | 74.755(2) | 78.084(4) | 90 |
V/nm3 | 2.1003(4) | 1.8597(6) | 2.5670(15) | 2.2140(6) |
Z, Dc/(g·cm-1) | 4, 2.157 | 2, 1.620 | 2, 1.795 | 8, 2.355 |
μ/mm-1 | 3.987 | 2.271 | 2.366 | 5.344 |
F(000) | 1328 | 906 | 1368 | 1512 |
θ range/(°) | 1.84—25.99 | 1.94—26.00 | 2.23—26.00 | 3.10—26.00 |
Data/restraints/parameters | 4094/7/336 | 7147/15/526 | 9785/20/808 | 2166/6/203 |
Reflections collected/unique | 11268/4094 (Rint=0.0309) | 10096/7147 (Rint=0.0185) | 13736/9785 (Rint=0.0263) | 11059/2166 (Rint=0.0344) |
GOF on F2 | 1.126 | 1.033 | 1.047 | 1.002 |
R1, wR2 [I>2σ(I)] | 0.0288, 0.0733 | 0.0324, 0.0814 | 0.0478, 0.1129 | 0.0183, 0.0450 |
R1, wR2(All data) | 0.0356, 0.0763 | 0.0387, 0.0845 | 0.0660, 0.1217 | 0.0244, 0.0477 |
Largest diff. peak and hole/( e·nm-3) | 657, -958 | 725, -867 | 1932, -1148 | 397, -422 |
Table 1 Crystal data and structure refinement for complexes 1—4
Complex | 1 | 2 | 3 | 4 |
---|---|---|---|---|
Empirical formula | C18H14N2 | C38H31N2O11SmZn | C42H34N6O29Sm2 | C6H12NO9Sm |
Formula mass | 682.03 | 907.37 | 1387.45 | 392.52 |
Crystal system | Monoclinic | Triclinic | Triclinic | Orthorhombic |
Space group | P21/c | P | P | Pbca |
a/nm | 0.99546(10) | 1.0887(2) | 0.9410(3) | 0.81136(13) |
b/nm | 2.2139(2) | 1.3527(3) | 1.5371(5) | 1.3133(2) |
c/nm | 0.97660(10) | 1.3910(3) | 1.8882(7) | 2.0779(3) |
α/(°) | 90 | 70.219(2) | 75.188(4) | 90 |
β/(°) | 102.6150(10) | 84.491(2) | 80.863(4) | 90 |
γ/(°) | 90 | 74.755(2) | 78.084(4) | 90 |
V/nm3 | 2.1003(4) | 1.8597(6) | 2.5670(15) | 2.2140(6) |
Z, Dc/(g·cm-1) | 4, 2.157 | 2, 1.620 | 2, 1.795 | 8, 2.355 |
μ/mm-1 | 3.987 | 2.271 | 2.366 | 5.344 |
F(000) | 1328 | 906 | 1368 | 1512 |
θ range/(°) | 1.84—25.99 | 1.94—26.00 | 2.23—26.00 | 3.10—26.00 |
Data/restraints/parameters | 4094/7/336 | 7147/15/526 | 9785/20/808 | 2166/6/203 |
Reflections collected/unique | 11268/4094 (Rint=0.0309) | 10096/7147 (Rint=0.0185) | 13736/9785 (Rint=0.0263) | 11059/2166 (Rint=0.0344) |
GOF on F2 | 1.126 | 1.033 | 1.047 | 1.002 |
R1, wR2 [I>2σ(I)] | 0.0288, 0.0733 | 0.0324, 0.0814 | 0.0478, 0.1129 | 0.0183, 0.0450 |
R1, wR2(All data) | 0.0356, 0.0763 | 0.0387, 0.0845 | 0.0660, 0.1217 | 0.0244, 0.0477 |
Largest diff. peak and hole/( e·nm-3) | 657, -958 | 725, -867 | 1932, -1148 | 397, -422 |
Assignment(theoretical value) | λ/nm(Complex 1) | λ/nm(Complex 2) | λ/nm(Complex 3) | λ/nm(Complex 4) |
---|---|---|---|---|
6H5/2→6F3/2(1516 nm) | 1478, 1538 | 1502, 1554 | 1512, 1558 | 1484, 1516 |
6H5/2→6F5/2(1411 nm) | 1370 | 1392 | 1394 | 1378 |
6H5/2→6F7/2(1260 nm) | 1224 | 1240 | 1244 | 1232 |
6H5/2→6F9/2(1100 nm) | 1074 | 1082 | 1082 | 1078 |
6H5/2→6F11/2(955 nm) | 936 | 942 | 942 | 940 |
6H5/2→4G7/2(501 nm) | 472 | 476 | 470 | 478 |
6H5/2→4F7/2(404 nm) | 402 | 402 | 404 | |
6H5/2→4F9/2(361 nm) | 373 | |||
π→π* | 270, 370 | 266, 342 | 254, 318 |
Table 2 Assignments of absorption bands for the UV-Vis-NIR spectra of complexes 1—4
Assignment(theoretical value) | λ/nm(Complex 1) | λ/nm(Complex 2) | λ/nm(Complex 3) | λ/nm(Complex 4) |
---|---|---|---|---|
6H5/2→6F3/2(1516 nm) | 1478, 1538 | 1502, 1554 | 1512, 1558 | 1484, 1516 |
6H5/2→6F5/2(1411 nm) | 1370 | 1392 | 1394 | 1378 |
6H5/2→6F7/2(1260 nm) | 1224 | 1240 | 1244 | 1232 |
6H5/2→6F9/2(1100 nm) | 1074 | 1082 | 1082 | 1078 |
6H5/2→6F11/2(955 nm) | 936 | 942 | 942 | 940 |
6H5/2→4G7/2(501 nm) | 472 | 476 | 470 | 478 |
6H5/2→4F7/2(404 nm) | 402 | 402 | 404 | |
6H5/2→4F9/2(361 nm) | 373 | |||
π→π* | 270, 370 | 266, 342 | 254, 318 |
[1] | Lakshminarayana1 G., Yang R., Qiu J. R., Brik M. G., Kumar G. A., Kityk I. V., J. Phys. D: Appl. Phys., 2009, 42, 1—12 |
[2] | Lin C. C., Tang Y. S., Hu S. F., Liu R. S., J. Lumin., 2009, 129, 1682—1684 |
[3] | Chen Y., Wang J., Liu C., Kuang X., Su Q., Appl. Phys. Lett., 2011, 98, 081917-1—081917-3 |
[4] | Du Y. Y., Huang K. K., Zhang J. Q., Wang C. C., Chu X. F., Hou C. M., Feng S. H., Chem. J. Chinese Universities, 2013, 34(3), 509—513 |
(杜燕燕, 黄科科, 张佳旗, 王楚楚, 初学峰, 侯长民, 冯守华. 高等学校化学学报, 2013, 34(3), 509—513) | |
[5] | Jiang Y. Y., Liu G. X., Wang J. X., Dong X. T., Yu W. S., Chem. J. Chinese Universities, 2013, 34(4), 794—799 |
(姜营营, 刘桂霞, 王进贤, 董相廷, 于文生. 高等学校化学学报, 2013, 34(4), 794—799) | |
[6] | Sun J., Liu Z., Du H., J. Rare Earth, 2011, 29, 101—102 |
[7] | Som T., Karmakar B., Spect. Act. A, 2010, 75, 640—646 |
[8] | Xia Z., Chen D., J. Am. Ceram. Soc., 2010, 93, 1397—1401 |
[9] | Ding J., Bao J., Sun S., Luo Z., Gao C., J. Comb. Chem., 2009, 11, 523—526 |
[10] | Xiao Z. H., Tan S. T., Wang X. Y., Zou Y. P., Spectroscopy and Spectral Analysis, 2005, 25, 145—148 |
(肖尊宏, 谭松庭, 王霞瑜, 邹应萍. 光谱学与光谱分析, 2005, 25, 145—148) | |
[11] | Wang G., Qin W., Zhang D., Wang L., Wei G., Zhu P., Kim R., J. Phys. Chem. C, 2008, 112, 17042—17045 |
[12] | Yu M., Lin J., Wang Z., Fu J., Wang S., Zhang H. J., Han Y. C., Chem. Mater., 2002, 14, 2224—2231 |
[13] | Fan W., Bu Y., Song X., Sun S., Zhao X., Crystal Growth & Design, 2007, 7, 2361—2366 |
[14] | Hou Z., Yang P., Li C., Wang L., Lian H., Quan Z., Lin J., Chem. Mater., 2008, 20, 6686—6696 |
[15] | Grubisic A., Ko Y. J., Wang H., Bowen K. H., J. Am. Chem. Soc., 2009, 131, 10783—10790 |
[16] | Petoud S., Cohen S. M., Bünzli J. C. G., Raymond K. N., J. Am. Chem. Soc., 2003, 125, 13324—13325 |
[17] | Chi Y. X., Niu S. Y., Jin J., Inorg. Chim. Acta, 2009, 362, 3821—3828 |
[18] | Bassett A. P., Magennis S. W., Glover P. B., Lewis D. J., Spencer N., Parsons S., Williams R. M., Cola L. D., Pikramenou Z., J. Am. Chem. Soc., 2004, 126, 9413—9424 |
[19] | Quici S., Cavazzini M., Marzanni G., Accorsi G., Armaroli N., Ventura B., Barigelletti F., Inorg. Chem., 2005, 44, 519—537 |
[20] | Wang H., Yang J., Zhang C. M., Lin J., J. Solid State Chem., 2009, 182, 2716—2724 |
[21] | Jia G., You H., Yang M., Zhang L., Zhang H., J. Phys. Chem. C, 2009, 113, 16638—16644 |
[22] | Petoud S., Cohen S. M., Bünzli J. C. G., Raymond K. N., J. Am. Chem. Soc., 2003, 125, 13324—13325 |
[23] | Petoud S., Muller G., Moore E. G., Xu J., Sokolnicki J., Riehl J. P., Le U. N., Cohen S. M., Raymond K. N., J. Am. Chem. Soc., 2007, 129, 77—83 |
[24] | Yu J., Zhou L., Zhang H., Zheng Y., Li H., Deng R., Peng Z., Li Z., Inorg. Chem., 2005, 44, 1611—1618 |
[25] | Fang J., You H., Chen J., Lin J., Ma D., Inorg. Chem., 2006, 45, 3701—3704 |
[26] | Sun S. J., Zhang D. H., Zhang J. J., Ye H. M., Wang S. P., Wu K. Z., J. Mol. Struc., 2010, 977, 17—25 |
[27] | Jin Y., Zhang J., Lu S., Zhao H., Zhang X., Wang X. J., J. Phys. Chem. C, 2008, 112, 5860—5864 |
[28] | Huhtinen P., Kivelä M., Kuronen O., Hagren V., Takalo H., Tenhu H., Lävgren T., Härmä H., Anal. Chem., 2005, 77, 2643—2648 |
[29] | Çolak A. T., Yesilel O. Z., Pamuk G., Günay H., Büyükgüngör O., Polyhedron, 2011, 30, 1012—1022 |
[30] | Geranmayeh S., Abbasi A., Skripkin M. Y., Badiei A., Polyhedron, 2012, 45, 204—212 |
[31] | Bai Y. Y., Huang Y., Yan B., Song Y. S., Weng L. H., Inorg. Chem. Commun., 2008, 11, 1030—1032 |
[32] | Deacon G. B., Phillips R. J., Coord. Chem. Rev., 1980, 33, 227—250 |
[33] | Kumari N., Ward B. D., Kar S., Mishra L., Polyhedron, 2012, 33, 425—434 |
[34] | Zhang J. L., Chen B. W., Luo X., Du K., Chem. Res. Chinese Universities, 2012, 28(6), 1054—1057 |
[35] | Li Y. X., Xue M., Guo L. J., Huang L., Chen S. R., Qiu S. L., Chem. Res. Chinese Universities, 2013, 29(2), 196—200 |
[36] | Shuvaev S., Utochnikova V., Marciniak Ł., Freidzon A., Sinev I., Deun R. V., Freire R. O., Zubavichus Y., Grünert W., Kuzmina N., Dalton Trans., 2014, 43, 3121—3136 |
[37] | Maxim C., Branzea D. G., Tiseanu C., Rouzières M., Clérac R., Andruh M., Avarvari N., Inorg. Chem., 2014, 53, 2708—2717 |
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