Effect of Derivatives of Glycerol Sulfite as Electrolyte Additive on Electrochemical Performance of Lithium Ion Battery†

doi:10.7503/cjcu20180321

Abstract

Abstract:

Three compounds, bis-[(2-oxido-1,3,2-dioxathiolan-4-yl)methyl]terephthalate(BMTP), tris[(2-oxido-1,3,2-dioxathiolan-4-yl)methyl]benzene-1,3,5-tricarboxylate(TMBT1) and tetrakis[(2-oxido-1,3,2-dioxathiolan-4-yl)methyl]benzene-1,2,4,5-tetracarboxylate(TMBT2), were designed and synthesized. Those compounds were added in lithium ion battery and their effect was thoroughly investigated by rate of charge and discharge test, galvanostatic charge and discharge test, electrochemical impedance spectroscopy(EIS) and scanning electron microscopy(SEM). The results showed that a dense and stable solid electrolyte interface(SEI) layer could be formed on the surface of the spheroidized graphite electrode with TMBT1, improving the electrode-electrolyte interface. And the increase of impedance with TMBT1 as electrolyte additive after 80 cycles was small. The performance test of battery show that the addition of TMBT1 can improve the rate performance and cycle stability of the battery, while the addition of BMTP and TMBT2 did not make the battery performance better. The results also suggest that number of cycle sulfite group on benzene ring has a huge influence on the performance of the lithium ion battery.

Key words: Electrolyte additive, Derivatives of glycerol sulfite, Lithium ion battery, Solid electrolyte interface(SEI) layer

CLC Number:

O646

TrendMD:

AI Shujuan, ZONG Chengxing, WU Wei, FENG Jingjing, JIN Can, FU Fengzhi, LIU Jing, SUN Donglan, ZHENG Qin, GUO Yeping. Effect of Derivatives of Glycerol Sulfite as Electrolyte Additive on Electrochemical Performance of Lithium Ion Battery^†[J]. Chem. J. Chinese Universities, 2018, 39(11): 2520.

Figures/Tables 7

Fig.1 1H NMR spectra of 1,2-cyclic sulfite glycerol(A), BMTP(B), TMBT1(C) and TMBT2(D)The insets show the structures of the corresponding compounds.

Fig.2 Rate capability of lithium ion batteries with blank electrolyte and different concentration of electrolyte additivesElectrolyte additive: (A) BMTP; (B) TMBT1; (C) TMBT2.

Fig.3 Charge and discharge curves of lithium ion batteries with blank electrolyte and different additives(A) First-cycle with different additives; (B) different cycles with 1.0% BMTP; (C) different cycles with 1.0% TMBT1;(D) different cycles with 1.0% TMBT2.

Fig.4 Cycling efficiency of lithium ion battery with blank electrolyte and different electrolyte additives

Fig.5 Rate capability of lithium ion batteries with blank electrolyte and different electrolyte additives

Fig.6 Nyquist plot of lithium ion batteries with blank electrolyte and different electrolyte additives(A) After 2 cycles; (B) after 80 cycles. a. Blank electrolyte; b. 1.0% BMTP; c. 1.0% TMBT1; d. 1.0% TMBT2.

Fig.7 SEM images of graphite electrodes with blank electrolyte and electrolyte with different additives for lithium ion battery(A) Electrode before cycle; (B) electrode with blank electrolyte after 80 cycles; (C) electrode with electrolyte+1.0% BMTP after 80 cycles; (D) electrode with electrolyte+1.0% TMBT1 after 80 cycles; (E) electrode with electrolyte+1.0% TMBT2 after 80 cycles.

References 43

[1]	Lukic S. M., Cao J., Bansal R. C., Rodriguez F., Emadi A., IEEE Transactions on Industrial Electronics, 2008, 55(6), 2258—2267
[2]	Xiong S. Z., Xie K., Hong X. B., Chem. J. Chinese Universities, 2011, 32(11), 2645—2649
	(熊仕昭, 谢凯, 洪晓斌. 高等学校化学学报, 2011, 32(11), 2645—2649)
[3]	Scrosati B., Garche J., Journal of Power Sources, 2010, 195(9), 2419—2430
[4]	Wu K., Zhang Y., Zeng Y. Q., Yang J., Progress in Chemistry, 2011, 23(2), 401—409
	(吴凯, 张耀, 曾毓群, 杨军. 化学进展, 2011, 23(2), 401—409)
[5]	Song Y. H., Yang Y. X., Hu Z. C., Power System Technology, 2011, 35(4), 1—7
	(宋永华, 阳岳希, 胡泽春. 电网技术, 2011, 35(4), 1—7)
[6]	Hu M., Pang X. L., Zhou Z., Journal of Power Sources, 2013, 237(3), 229—242
[7]	Liu G. Q., Wen L., Liu Y. M., Journal of Solid State Electrochemistry, 2010, 14(12), 2191—2202
[8]	Xu M. Q., Xing L. D., Li W. S., A Non-aqueous Electrolyte and Preparation Method and Application for High-voltage Lithium-ion Battery, CN 101702447A,2010-05-05
	(徐梦清, 邢丽丹, 李伟善. 用于高电压锂离子电池的非水电解液及其制备方法与应用: CN 101702447A, 2010-05-05)
[9]	Wang D., Li X. H., Wang Z. X., Guo H. J., Xu Y., Fan Y. L., Ru J. J., Electrochimica Acta, 2016, 188, 48—56
[10]	Lee B. R., Noh H. J., Myung S. T., Amine K., Sun Y. K., Journal of the Electrochemical Society, 2011, 158(2), A180—A186
[11]	Lu L. G., Han X. B., Li J. Q., Hua J. F., Ouyang M. G., Journal of Power Sources, 2013, 226(3), 272—288
[12]	Oh S. W., Park S. H., Kim J. H., Bae Y. C., Sun Y. K., Journal of Power Sources, 2006, 157(1), 464—470
[13]	Wang D., Li X. H., Wang Z. X., Gou H. J., Xu Y., Fan Y. L., Electrochimica Acta, 2016, 196, 101—109
[14]	Yan G. C., Li X. H., Wang Z. X., Guo H. J., Wang J. X., Peng W. J., Electrochimca Acta, 2015, 166, 190—196
[15]	Zuo X. X., Fan C. J., Liu J. S., Xiao X., Wu J. H., Nan J. M., Journal of Power Sources, 2013, 229(3), 308—312
[16]	Wrodnigg G. H., Besenhard J. O., Winter M., Journal of The Electrochemical Society, 1999, 146(2), 470—472
[17]	Zhang B. B., Zhou Y., Li X., Ren X. F., Nian H. E., Chinese Journal of Power Sources, 2014, 6, 1167—1173
	(张斌斌, 周圆, 李翔, 任秀峰, 年洪恩. 电源技术, 2014, 6, 1167—1173)
[18]	Zhao B. H., Fang L., Chinese Battery Industry, 2013, 18(1), 78—81
	(赵本好, 方丽. 电池工业, 2013, 18(1), 78—81)
[19]	Li A. J., Du P., Chen Z. J., Zhao R. R., Huang W. D., Zou L. Y., Huang D. H., Chen H. Y., Ionics, 2015, 21(9), 2431—2438
[20]	Zuo X. X., Li W. S., Liu J. S., Xu M. Q., Chinese Battery Industry, 2006, 11(2), 97—99
	(左晓希, 李伟善, 刘建生, 许梦清. 电池工业, 2006, 11(2), 97—99)
[21]	Yu B. T., Qiu W. H., Li F. S., Cheng L., Journal of Power Sources, 2006, 158(2), 1373—1378
[22]	Wrodnigg G. H., Wrodnigg T. M., Besenhard J. O., Winter M., Electrochemistry Communications, 1999, 1(3—4), 148—150
[23]	Guo M. Y., Zong C. X., Ai S. J., Fu F. Z., Wang Q., Liu J., Sun D. L., Guo Y. L., Guo Y. P., Chem. J. Chinese Universities, 2017, 38(10), 1857—1863
	(郭梦雅, 宗成星, 艾淑娟, 付凤至, 王琪, 刘靖, 孙冬兰, 郭艳玲, 郭也平. 高等学校化学学报, 2017, 38(10), 1857—1863)
[24]	Dong T., Zhang L., Chen S. M., Lu X. M., Zhang S. J., Ionics., 2015, 21(8), 2109—2117
[25]	Zong C. X., Guo M. Y., Ai S. J., Wu W., Jin C., Liu J., Sun D. L., Journal of Tianjin University of Science and Technology, 2018, 33(6), 73—78
	(宗成星, 郭梦雅, 艾淑娟, 吴为, 金灿, 刘靖, 孙冬兰. 天津科技大学学报, 2018, 33(6), 73—78)
[26]	Jing J., Mao L. P., Cui X. L., Li S. Y., Li L. X., New Chemical Materials, 2015, 5, 11—13
	(净洁, 毛丽萍, 崔孝玲, 李世友, 李玲霞. 化工新型材料, 2015, 5, 11—13)
[27]	Zhuang Q. C., Wu S., Chemistry Bulletin, 2003, 66(11), 743—747
	(庄全超, 武山. 化学通报, 2003, 66(11), 43—747)
[28]	Lemaire M., Bolte J., Tetrahedron: Asymmetry, 1999, 10(24), 4755—4762
[29]	Naji A., Ghanbaja J., Willmann P., Billaud D., Electrochimica Acta, 2000, 45(12), 1893—1899
[30]	Shu Z. X., Mcmillan R., Murray J. J., Davidson I., Journal of the Electrochemical Society, 1995, 142(9), L161—L162
[31]	Li L., Wu F., Chen R. J., Wu S. X., Chem. J. Chinese Universities, 2007, 28(2), 293—296
	(李丽, 吴锋, 陈人杰, 吴生先. 高等学校化学学报, 2007, 28(2), 293—296)
[32]	Zhang Q., Synthesis of Fluorine-containing Ester Additive and Application in Lithium Ion Batteries, University of Jinan, Jinan, 2016
	(张倩. 含氟酯类添加剂的合成及其在锂离子电池中的应用研究, 济南: 济南大学, 2016)
[33]	Zhen H. H., Lithium-ion Battery Electrolyte, Chemical Industry Press, Beijing, 2007
	(郑洪河. 锂离子电池电解质. 北京: 化学工业出版社, 2007)
[34]	Li F. Q., Lan Y. Q., Zhang Z. A., Gao H. Q., Yang J., Acta Physico-Chimica Sinica, 2008, 24(7), 1302—1306
	(李凡群, 赖延清, 张治安, 高宏权, 杨娟. 物理化学学报, 2008, 24(7), 1302—1306)
[35]	Huang K. L., Lv Z. Z., Liu S. Q., Battery, 2001, 31(3), 142—145
	(黄可龙, 吕正中, 刘素琴. 电池, 2001, 31(3), 142—145)
[36]	Yang J., Jie J. Y., Wang J. L., Chemical Power Test Principle and Technology, Chemical Industry Press, Beijing, 2006
	(杨军, 解晶莹, 王久林. 化学电源测试原理与技术, 北京: 化学工业出版社, 2006)
[37]	Verma P., Maire P., Novák P., Electrochimica Acta, 2010, 55(22), 6332—6341
[38]	Ryou M. H., Lee D. J., Lee J. N., Lee Y. M., Park J. K., Choi J. W., Advanced Energy Materials, 2012, 2(6), 610
[39]	Chen S. B., Wu X. M., Chen S., Ding Q. C., He H. L., Applied Chemical Industry, 2016, 45(1), 18—25
	(陈守彬, 吴显明, 陈上, 丁其晨, 何海亮. 应用化工, 2016, 45(1), 18—25)
[40]	Zhang Y. Y., Zhou Y., Deng X. Y., Du X. Y., Chemistry Bulletin, 2007, 70(12), 929—935
	(张昕岳, 周园, 邓小宇, 杜秀月. 化学通报, 2007, 70(12), 929—935)
[41]	Wang E. T., Liu G. Q., Ren Y. Z., Chemical Research, 2007, 18(1), 93—97
	(王恩通, 刘根庆, 任引哲. 化学研究, 2007, 18(1), 93—97)
[42]	Yang C. H., Study on AC Impedance Characteristics of LiFePO4 as Cathode Materials for Lithium Ion Batteries, Shandong University of Science and Technology, Qingdao, 2015
	(杨传浩. 锂离子电池正极材料LiFePO4交流阻抗的研究, 青岛: 山东科技大学, 2015)
[43]	Xu J., Yao W. H., Yao Y. W., Wang Z. C., Yang Y., Acta Physico-Chimica Sinica, 2009, 25(2), 201—206
	(许杰, 姚万浩, 姚宜稳, 王周成, 杨勇. 物理化学学报, 2009, 25(2), 201—206)