Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (6): 1258.doi: 10.7503/cjcu20180773
• Physical Chemistry • Previous Articles Next Articles
ZHAO Xinyue, WANG Jinglun, YAN Xiaodan, ZHANG Lingzhi()
Received:
2018-11-19
Online:
2019-06-10
Published:
2019-03-27
Supported by:
CLC Number:
TrendMD:
ZHAO Xinyue,WANG Jinglun,YAN Xiaodan,ZHANG Lingzhi. Effect of Nitrile Group Functionalized Organosilicon as Electrolyte Additive on Low-temperature Performance of LiFePO4 Battery†[J]. Chem. J. Chinese Universities, 2019, 40(6): 1258.
Fig.1 Chemical structure of DESCN 1H NMR(400 MHz, CDCl3), δ: 3.78(q, 4H, —OCH2CH3), 2.38(t, 2H, —CH2CH2CN), 1.21(t, 6H, —OCH2CH3), 0.98(t, 2H, —CH2CH2CN), 0.18(s, 3H, —SiCH3); 13C NMR(100 MHz, CDCl3), δ: 120.9, 50.3, 10.9, 9.6, -6.0; 29Si NMR(79.5 MHz, CDCl3), δ: -9.14.
εa | ηb/(mPa·s) | σc/(mS·cm-1) | |||
---|---|---|---|---|---|
14.7 | 1.64 | 1.27 | 0 | 6.3 | -128 |
Table 1 Physical and chemical properties of DESCN compound
εa | ηb/(mPa·s) | σc/(mS·cm-1) | |||
---|---|---|---|---|---|
14.7 | 1.64 | 1.27 | 0 | 6.3 | -128 |
Fig.5 Nyquist plots of the LiFePO4 electrode at 25 ℃(A) and -20 ℃(B) Inset: R0: Electrolyte/electrode resistance; Rf and Cf: SEI film resistance and related capacitance; Rc and Cd: charge-transfer resistance and related capacitance; Ri and Ci: electronic resistance and related capacitance; ZW: Warburg diffusion impedance.
Fig.6 SEM images of surface morphology of LiFePO4 electrode (A) Original; (B) cycled in electrolyte without DESCN at -20 ℃; (C) cycled in electrolyte with 2% DESCN at -20 ℃.
Electrode | C(%) | O(%) | P(%) | Fe(%) |
---|---|---|---|---|
Before cycling | 15.73 | 59.45 | 13.51 | 11.30 |
Without DESCN after cycling | 19.35 | 58.89 | 12.16 | 9.60 |
With 2%DESCN after cycling | 18.64 | 57.00 | 13.12 | 11.25 |
Table 2 Element contents of the electrode surface
Electrode | C(%) | O(%) | P(%) | Fe(%) |
---|---|---|---|---|
Before cycling | 15.73 | 59.45 | 13.51 | 11.30 |
Without DESCN after cycling | 19.35 | 58.89 | 12.16 | 9.60 |
With 2%DESCN after cycling | 18.64 | 57.00 | 13.12 | 11.25 |
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