Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (5): 822.doi: 10.7503/cjcu20150809
• Articles: Inorganic Chemistry • Previous Articles Next Articles
WANG Bin*(), WANG Xiaohong, LIU Zongrui, DUAN Limei, XU Ling, BAI Suozhu
Received:
2015-10-22
Online:
2016-05-10
Published:
2016-04-21
Contact:
WANG Bin
E-mail:jluwangbin09@163.com
Supported by:
CLC Number:
TrendMD:
WANG Bin, WANG Xiaohong, LIU Zongrui, DUAN Limei, XU Ling, BAI Suozhu. Preparation and Electroswitchable Luminescence Properties of Nanocomposite Films of Polyoxometalates and Ru(phen)3C
Fig.2 UV-Vis spectra of 1×10-5 mol/L P8W48(a) and 1×10-5 mol/L Ru(phen)3Cl2(b)(A) and the [PEI/P8W48/PEI/PSS/Ru(phen)/PSS]n multilayers(B)Inset shows the absorbance at 268 and 450 nm as a function of layer number(n).
Fig.4 Fluorescence spectra of 1 μmol/L Ru(phen)3Cl2 solution(A) and the [(PEI/P8W48)m/PEI/PSS/Ru(phen)/PSS]15 thin films(B)(B) a. m=1; b. m=3; c. m=5.
Fig.5 UV-Vis spectra(A, C) and fluorescence spectra(B, D) of [(PEI/P8W48)3/PEI/PSS/Ru(phen)/PSS]15 thin film at applied potential -0.85 V(A, B) and 0.85 V(C, D) as a function of time
Fig.7 Fluorescence spectra of [(PEI/P8W48)m/PEI/PSS/Ru(phen)/PSS]15(m=1, 3, 5) thin film at open circuit(a), -0.85 V(b) and 0.85 V(c)(A) m=1; (B) m=3; (C) m=5. The insets are the normalized intagral area under redox potential 0.85 V and -0.85 V with different cycles.
Fig.8 Chronoamperometry curves(A) and absorbance at 590 nm(B) of the hybrid film [PEI/P8W48/PEI/PSS/Ru(phen)/PSS]15 under double potential steps from -0.85 V to 0.85 V
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