Preparation of Fe3O4@IRMOF-3/Pd and its catalytic performances as a Heterogeneous Multifunctional Catalyst

doi:10.7503/cjcu20150511

Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (3): 573.doi: 10.7503/cjcu20150511

• Physical Chemistry • Previous Articles Next Articles

Preparation of Fe₃O₄@IRMOF-3/Pd and its catalytic performances as a Heterogeneous Multifunctional Catalyst

ZHANG Yanmei¹, ZHANG Jing², LI Xiaofang², CHU Gang², TIAN Miaomiao², QUN Chunshan¹

1. College of Life Science, Dalian Nationalities University, Economical and Technological Development Zone, Dalian 116600, China;
2. School of Chemistry and Material Science, Liaoning Shihua University, Fushun 113001, China

Received:2015-07-01 Revised:2016-01-06 Online:2016-03-10 Published:2016-01-06
Supported by:
Supported by the National Natural Science Foundation of China(No.21203017), the Open Fund of State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences(No.N-11-3), the Program for Liaoning Excellent Talents in University, China and the Fundamental Research Funds for the Central Universities, China(No.DC201502020304).

Abstract

Abstract:

Pd nanoparticles supported on Fe₃O₄@IRMOF-3 fabricated by a step-wise assembly method was prepared and evaluated as a potential heterogeneous catalyst for Knoevenagel condensations, Suzuki-coupling and hydrogenations. The results demonstrated that the magnetic multifuctional material was active and stable as a heterogeneous catalyst for the reactions mentioned above. Remarkabaly, It was an effective and size selective catalyst for alkenes. Furthermore, it could be magnetically recovered and reused for at least 9 times without obvious loss of activity.

Key words: Fe₃O₄, IRMOF-3, Pd, Magnetic seperation, Knoevenagel condensation, Hydrogenation, Suzuki-coupling

CLC Number:

O643.3

TrendMD:

ZHANG Yanmei, ZHANG Jing, LI Xiaofang, CHU Gang, TIAN Miaomiao, QUN Chunshan. Preparation of Fe₃O₄@IRMOF-3/Pd and its catalytic performances as a Heterogeneous Multifunctional Catalyst[J]. Chem. J. Chinese Universities, 2016, 37(3): 573.

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Preparation of Fe₃O₄@IRMOF-3/Pd and its catalytic performances as a Heterogeneous Multifunctional Catalyst

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