Praperation of Fe3O4 Hexane Ferrofluid with Phase-transfer Method

doi:10.7503/cjcu20130317

Abstract

Abstract:

A novel and facile phase-transform method has been presented for the preparation of double-coated Fe₃O₄ hexane ferrofluid. Firstly, the double-coated Fe₃O₄ nanoparticles were synthesized via chemical coprecipitation and excess sodium oleate were used as surfactant to yield a stable water-based magnetic fluid. Based on this, hydrophilic Fe₃O₄ nanoparticles were transformed into hydrophobic ones which were extracted to hexane by adding acetic acid. Fourier transform infrared(FTIR) spectra show that -COO^- at the outer layer of Fe₃O₄ nanoparticles transforms into -COOH at proper pH value adjusted by acetic acid, which makes Fe₃O₄ nanoparticles hydrophobic and dispersive in polar or nonpolar carrier liquid. X-Ray diffractometer(XRD), vibrating sample magnetometer(VSM) and transmission electron microscope(TEM) were also used to characterize the magnetic nanopartieles and the ferrofluid. Our method ensures that Fe₃O₄ nanoparticles are coated compactly and mono-dispersive state without any agglomeration, which makes the thus obtained hexane ferrofluid stable and less delamination after several months. The ferrofluid with different solid content and dispersed in other oil-based carriers can be obtained through evaporating n-hexane.

Key words: Fe₃O₄, Sodium oleate, Double-coating, Ferrofluid

CLC Number:

O614

TrendMD:

CHEN Ming-Jie, XIONG Xiao-Min, SHEN Hui, LIU Hai-Feng. Praperation of Fe₃O₄ Hexane Ferrofluid with Phase-transfer Method[J]. Chem. J. Chinese Universities, 2013, 34(8): 1801.

[1]	WANG Hong, SAN Khin Nyein Ei, FANG Yun, ZHANG Xinyu, FAN Ye. Pickering Emulsion Stabilization and Interfacial Catalytic Oxidation by Janus Nano-Au [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220105.
[2]	XU Yan, YANG Hongguo, NIU Huibin, TIAN Hailin, PIAO Hongguang, HUANG Yingping, FANG Yanfen. Preparation Mechanism and Application of Alcohol⁃modified Fe₃O₄ Magnetic Nanoparticles [J]. Chem. J. Chinese Universities, 2021, 42(8): 2564.
[3]	WANG Can, WANG Dianyu, MIAO Weining, TIAN Ye. Intelligent Controllable Microreactor Based on Superhydrophilic Nanochannel [J]. Chem. J. Chinese Universities, 2021, 42(4): 1276.
[4]	LU Feng, GONG Yi, ZHAO Ting, ZHAO Ning, JU Wenwen, FAN Quli, HUANG Wei. Seedless Synthesis of Gold Nanorods with Narrow Absorption Using Binary Surfactant Mixture [J]. Chem. J. Chinese Universities, 2021, 42(3): 700.
[5]	SUN Qirui, ZHAO Nan, LIU Shuwei, XIN Hua, ZHANG Hao, ZHANG Lening. Polydopamine-coated Fe₃O₄/methylprednisolone/cyclophosphamide Superparticles for the Magnetic Targeting Treatment of Pulmonary Fibrosis [J]. Chem. J. Chinese Universities, 2021, 42(10): 3225.
[6]	ZHANG Xinyu, WANG Hong, FANG Yun, FAN Ye. Stimuli-responsive Fe₃O₄ Nanoparticle Modified by Conjugated Linoleic Acid [J]. Chem. J. Chinese Universities, 2020, 41(11): 2519.
[7]	WANG Xiaohui, WANG Kexin, LIU Junping, HONG Xia. Mesoporous-structure Enhanced Photothermal Effect of Fe₃O₄ Superparticles@mesoporous Silica [J]. Chem. J. Chinese Universities, 2019, 40(8): 1586.
[8]	HUANG Xiaolin,XIE Huan,CAO Hong,JIN Hongjie,LI Chun,WU Tinghua. Preparation, Characterization of Magnetic Core Gel Microspheres Loaded Ionic Liquids and Its Application in Cells Immobilization Technique^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 793.
[9]	HAN Donglai,LI Boxun,YANG Shuo,YAN Yongsheng,YANG Lili,LIU Yang,LI Chunxiang. Facile Synthesis of Fe₃O₄@Au Core-shell Nanocomposites as an SERS Substrate for the Detection of Thiram ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2067.
[10]	YUAN Jiayi, YE Baotong, WU Jing, LI Ying, CHEN Jinghua, CHEN Jingxiao. Study on Sulfated Glycosylated Fe₃O₄@SiO₂ Nanoparticles Inducing Tumor Cells Apoptosis^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2458.
[11]	YU Xiaodan, LIN Xinchen, FENG Wei, LI Weiguang. One-step Preparation and UV-Fenton Properties of Fe₃O₄/TiO₂@Bio-carbon Composities^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2500.
[12]	YANG Yuxiang, LIU Yicheng, ZHAO Min, YUAN Hongming, YAO Pingping, HUANG Yan, NI Chaoying. Thermal Reduation Preparation of Co²⁺/Dy³⁺ Doped Cubic Fe₃O₄ and Their Magnetic Targeting Retention^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1709.
[13]	ZHANG Yanmei, ZHANG Jing, LI Xiaofang, CHU Gang, TIAN Miaomiao, QUN Chunshan. Preparation of Fe₃O₄@IRMOF-3/Pd and its catalytic performances as a Heterogeneous Multifunctional Catalyst [J]. Chem. J. Chinese Universities, 2016, 37(3): 573.
[14]	WANG Chun-Lei, YAN Jun-Tao, ZHONG Shuang-Ling, LI Zhan-Feng, CUI Xue-Jun, WANG Hong-Yan. Fabrication of Magnetic Protein Microcapsules by Sonochemical Method [J]. Chem. J. Chinese Universities, 2013, 34(2): 462.
[15]	JIANG Ze-Quan, SONG Sheng, DOU Hong-Jing, SUN Kang, WANG Yi-Ming, HUANG Chao-Fan, WEI Zhen-Hua, QU Guan-Xiong. Synthesis of Polycarboxylic Ligand Capped Fe₃O₄ Nanoparticles with Excellent Water-dispersibility via a Ligand-exchange Approach [J]. Chem. J. Chinese Universities, 2012, 33(12): 2609.

Praperation of Fe₃O₄ Hexane Ferrofluid with Phase-transfer Method

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments