Hydrothermal Synthesis and Crystal Structure of a Novel Threedimensional Silver Coordination Polymer [Ag3(IN)2(CF3COO)]

Chem. J. Chinese Universities

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Hydrothermal Synthesis and Crystal Structure of a Novel Threedimensional Silver Coordination Polymer [Ag₃(IN)₂(CF₃COO)]

TIAN Ge, YUAN Hong-Ming, CHEN Yan, LI Guang-Hua, FENG Shou-Hua

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Received:2006-02-27 Revised:1900-01-01 Online:2006-11-10 Published:2006-11-10
Contact: FENG Shou-Hua

Abstract

Abstract: A three-dimensional silver coordination polymer, [Ag₃(IN)₂(CF₃COO)](IN=Isonicotinic acid), was synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction. The compound crystallizes in the triclinic space group P-1, with unit cell parameters a=0.91848(5) nm, b=1.01392(6) nm, c=1.06705(6) nm, Z=2, R₁=0.0365, wR₂=0.0955. The Ag centers are bridged by the IN and CF₃CO₂ ligands to form three-dimensional structure. There are strong Ag-Ag bond interaction in the framework.

Key words: Hydrothermal synthesis, Crystal structure, Silver coordination polymer

CLC Number:

O614

TrendMD:

TIAN Ge, YUAN Hong-Ming, CHEN Yan, LI Guang-Hua, FENG Shou-Hua. Hydrothermal Synthesis and Crystal Structure of a Novel Threedimensional Silver Coordination Polymer [Ag₃(IN)₂(CF₃COO)][J]. Chem. J. Chinese Universities, doi: .

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Hydrothermal Synthesis and Crystal Structure of a Novel Threedimensional Silver Coordination Polymer [Ag₃(IN)₂(CF₃COO)]

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