Synthesis, Crystal Structure and Combustion Catalytic Activity of a Novel Energetic Complex [Pb(AZTZ)(bpy)(H2O)·2H2O]n

Chem. J. Chinese Universities

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Synthesis, Crystal Structure and Combustion Catalytic Activity of a Novel Energetic Complex [Pb(AZTZ)(bpy)(H₂O)·2H₂O]_n

ZHAO Feng-Qi¹, CHEN San-Ping², FAN Guang², XIE Gang², JIAO Bao-Juan³, GAO Sheng-Li²*

1. Xi’an Modern Chemistry Research Institute, Xi’an 710065, China;
2. Department of Chemistry, Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, Ministry of Education, Northwest University, Xi’an 710069, China;
3. Department of Chemistry, Xi’an University of Arts and Science, Xi’an 710065, China

Received:2008-01-18 Revised:1900-01-01 Online:2008-08-10 Published:2008-08-10
Contact: GAO Sheng-Li

Abstract

Abstract: A novel energetic complex with a formula of [Pb(AZTZ)(bpy)(H₂O)·2H₂O]_n(1)(AZTZ=5,5’-azotetrazole dianion, bpy=2,2’ bipyridine ) was synthesized and its structure was characterized by elemental analysis, IR, thermalgravimetric analysis and single crystal X-ray diffraction method. Crystal data: triclinic system, space group P1, a=0.7341(6) nm, b=1.0050(8) nm, c=1.3367(1) nm, α=95.354(1)°, β=101.450(1)°, γ=101.233(1)°, V=0.8927(1) nm³, Z=2, S=1.030, final R indices[I>2σ(I)], R₁=0.0301, wR₂=0.0605, for all reflections R₁=0.0351, wR₂=0.0630. In addition, the catalytic performance of complex 1 on the combustion of solid double-based propellant is presented, which shows that complex 1 can enhance the burning-rate of solid double-based propellant.

Key words: Energetic complex, Crystal structure, Energetic catalyst

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ZHAO Feng-Qi¹, CHEN San-Ping², FAN Guang², XIE Gang², JIAO Bao-Juan³, GAO Sheng-Li²*. Synthesis, Crystal Structure and Combustion Catalytic Activity of a Novel Energetic Complex [Pb(AZTZ)(bpy)(H₂O)·2H₂O]_n[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Crystal Structure and Combustion Catalytic Activity of a Novel Energetic Complex [Pb(AZTZ)(bpy)(H₂O)·2H₂O]_n

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