Synthesis and Crystal Structure of Diaquo Bis(1, 10-phenanthroline-N-monoxide)copper ( Ⅱ )nitrate

Abstract

Abstract: In the present work, we describe the synthesis and crystal structure of the title compound. The complex crystallizes in the monoclinic space group C2/c with Z=4. Lattice parameters are: a= 15. 724 (2) Å, b=8. 995(2)Å, c=18. 432(3)Å ,β= 112. 06(2)°. The structure was solved by the direct method and Fourier techniques and refined by full-matrix least-squares to R= 0. 077 for 2352 reflections. The Cu²⁺ ion is six-coordinate, being bonded to two oxygen atoms, two nitrogen atoms belong to two ligands and two oxygen atoms belong to two water molecules; The coordinated configuration of Cu²⁺ ion is a slightly distorted octahedron. The nitrate groups are not coordinated to Cu²⁺ ion.

Key words: 1,10-phenanthroline-N-monoxide, Complex of copper(Ⅱ) nitrate, Crystal structure

TrendMD:

Wang Xin, Gan Xinmin, Tan Minyu, Yuan Jingli, Wang Guilan, Yuan Wanzhong. Synthesis and Crystal Structure of Diaquo Bis(1, 10-phenanthroline-N-monoxide)copper ( Ⅱ )nitrate[J]. Chem. J. Chinese Universities, 1990, 11(2): 111.

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