Extraction Mechanism and Property of Phenyl Alanine with n-Octyl-L-hydroxyproline

Chem. J. Chinese Universities

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Extraction Mechanism and Property of Phenyl Alanine with n-Octyl-L-hydroxyproline

CUI Yu¹, YIN Shao-Hong¹, SUN Guo-Xin¹*, TIAN Xiao-Qiang^1,2, CUI Yu-Hua¹

1. School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
2. Institute 53 of China North Industries Group Corporation, Jinan 250031, China

Received:2007-10-10 Revised:1900-01-01 Online:2008-05-10 Published:2008-05-10
Contact: SUN Guo-Xin

Abstract

Abstract: A novel chiral extractant n-octyl-L-hydroxyproline was synthesized. The extraction mechanism and property of D- or L-phenyl alanine with n-octyl-L-hydroxyproline with n-octane and n-octanol(volume ratio, 7∶3) as the diluent was investigated. The effect of concentrations of extractant and copper ion and pH on the extraction of phenyl alanine was studied. The influence of temperature on the extraction shows that the extraction is endothermic reaction. The extracted species were characterized and the structure was suggested. This result will be helpful for the further study on extracting and separating D,L-phenyl alanine.

Key words: n-Octyl-L-hydroxyproline, Extraction, Phenyl alanine

CLC Number:

O614
Q517

TrendMD:

CUI Yu¹, YIN Shao-Hong¹, SUN Guo-Xin¹*, TIAN Xiao-Qiang^1,2, CUI Yu-Hua¹. Extraction Mechanism and Property of Phenyl Alanine with n-Octyl-L-hydroxyproline[J]. Chem. J. Chinese Universities, doi: .

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Extraction Mechanism and Property of Phenyl Alanine with n-Octyl-L-hydroxyproline

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