Synthesis and Properties of a Novel Charge Trasfer Type of Molecule FcBAK/Molybdophosphoric Acid Composite

Chem. J. Chinese Universities

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Synthesis and Properties of a Novel Charge Trasfer Type of Molecule FcBAK/Molybdophosphoric Acid Composite

WU Ying¹*, LI Zheng¹, JU Jin-Mei², WEN Di-Jiang²

1. Institute of Chemistry and Chemical Engineering,
2. Institute of Material Engineering, Suzhou University, Suzhou 215123, China

Received:2007-09-24 Revised:1900-01-01 Online:2008-04-10 Published:2008-04-10
Contact: WU Ying

Abstract

Abstract: A novel organic-inorganic molecule with a composition of [Fe(C₅H₅)₂COC₂H₂C₆H₅]₃HPMo₁₂O₄₀·2H₂O was synthesized by solid-state reaction at room temperature. The compound was characterized via elemental analysis, IR, ICP, AAS, TG. The results of solid electronic absorption spectra and ESR spectra show that charge transfer between Fe(C₅H₅)₂COC₂H₂C₆H₅(1-ferrocenyl-3-benzoyl-2-alkene-1-ketone, short of FcBAK) and polyoxometalate anion(molybdophosphoric) took place and the polyoxometalate anion formed a mixed valence compound. Magnetic measurement result shows that the compound is a ferromagnetic materials, with its M_s=0.41 A·m²/kg, H_c=0.0105 T. The relationship between the structure and magnetic propety has been discussed. This work provides a way for design and synthesis of novel organic-inorganic magnetic materials.

Key words: Organic-inorganic molecular composite molecule, Ferrocene derivative, Molybdophosphoric acid, Charge transfer, Ferromagnetic property

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WU Ying¹*, LI Zheng¹, JU Jin-Mei², WEN Di-Jiang². Synthesis and Properties of a Novel Charge Trasfer Type of Molecule FcBAK/Molybdophosphoric Acid Composite[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Properties of a Novel Charge Trasfer Type of Molecule FcBAK/Molybdophosphoric Acid Composite

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