Crystal Structure of Nickel(Ⅱ) Complex with Mono-Schiff Bases from Picolinaldehyde N-Oxide and 1,2-Propanediamine

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1355.

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Crystal Structure of Nickel(Ⅱ) Complex with Mono-Schiff Bases from Picolinaldehyde N-Oxide and 1,2-Propanediamine

YAN Shi-Ping, JIANG Zong-Hui, LIAO Dai-Zheng, WANG Geng-Lin, WANG Ru-Ji, WANG Hong-Gen, YAO Xin-Kan

Department of Chemistry, Center of Laboratory, Nankai University, Tianjin, 300071

Received:1991-11-30 Revised:1992-03-30 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: The crystal structure of nickel(Ⅱ)complex of mono-schiff bases from picolinaldehyde N-oxide and 1,2-propanediamine was determined by X-ray diffraction.The crystal belongs to monoclinic system,space group P2₁/c,a=0.8199(1)nm,b=3.364(3)nm,c=0.9325(2)nm,β=97.32(2)°,V=2.551 nm³,M=616.04,Z=4,D_x=1.57 g/cm³,μ=10.33 cm^-1,F(000)=1272,R=0.068.The coordination number of Ni(Ⅱ)is six.Ni(Ⅱ)ion in the complex is in octahedral environment of coordination.

Key words: Crystal structure, Ni(Ⅱ) Complex, Derivative of pyridine N-oxide

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YAN Shi-Ping, JIANG Zong-Hui, LIAO Dai-Zheng, WANG Geng-Lin, WANG Ru-Ji, WANG Hong-Gen, YAO Xin-Kan . Crystal Structure of Nickel(Ⅱ) Complex with Mono-Schiff Bases from Picolinaldehyde N-Oxide and 1,2-Propanediamine[J]. Chem. J. Chinese Universities, 1992, 13(11): 1355.

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Crystal Structure of Nickel(Ⅱ) Complex with Mono-Schiff Bases from Picolinaldehyde N-Oxide and 1,2-Propanediamine

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