Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (12): 2150.doi: 10.7503/cjcu20160447
• Analytical Chemistry • Previous Articles Next Articles
WU Ruofei, CHU Yanqiu, XU Chongsheng, LIU Zhipan, DING Chuanfan*()
Received:
2016-06-26
Online:
2016-12-10
Published:
2016-11-21
Contact:
DING Chuanfan
E-mail:cfding@fudan.edu.cn
Supported by:
CLC Number:
TrendMD:
WU Ruofei, CHU Yanqiu, XU Chongsheng, LIU Zhipan, DING Chuanfan. Fragmentation Reaction of Complexes of Alkali Metal Cations with Tripeptides in Gas Phase†[J]. Chem. J. Chinese Universities, 2016, 37(12): 2150.
Fig.2 Mass spectra for competition reaction of tripeptides with alkali metal ions(A) GGG with Li+, Na+, K+, Rb+ and Cs+ in a molar ratio of 1∶1∶1∶1∶1∶1; (B) GFG with Li+, Na+ and K+ in a molar ratio of 1∶1∶1∶1; (C) GGF with Li+, Na+ and K+ in a molar ratio of 1∶1∶1∶1.
Fig.3 Normalized percentages of the intact complexes plotted against collision energy of mass frame(A) GGG with a proton or an alkali ion; (B) GGG, GFG or GGF with a Na+; (C) GGG with one or two Na+.
Complex | lg | SDb | RSD(%)c | Complex | lg | SDb | RSD(%)c |
---|---|---|---|---|---|---|---|
[GGG+Li]+ | 5.32 | 0.20 | 3.4 | [GFG+K]+ | 5.10 | 0.02 | 0.3 |
[GGG+Na]+ | 5.30 | 0.07 | 1.3 | [GGF+Li]+ | 5.25 | 0.13 | 2.6 |
[GGG+K]+ | 5.14 | 0.12 | 2.3 | [GGF+Na]+ | 5.17 | 0.19 | 3.8 |
[GFG+Li]+ | 5.20 | 0.10 | 2.0 | [GGF+K]+ | 5.11 | 0.06 | 1.1 |
[GFG+Na]+ | 5.15 | 0.04 | 0.7 |
Table 1 lg K a 1 values of GGG,GFG or GGF with Li+, Na+ or K+
Complex | lg | SDb | RSD(%)c | Complex | lg | SDb | RSD(%)c |
---|---|---|---|---|---|---|---|
[GGG+Li]+ | 5.32 | 0.20 | 3.4 | [GFG+K]+ | 5.10 | 0.02 | 0.3 |
[GGG+Na]+ | 5.30 | 0.07 | 1.3 | [GGF+Li]+ | 5.25 | 0.13 | 2.6 |
[GGG+K]+ | 5.14 | 0.12 | 2.3 | [GGF+Na]+ | 5.17 | 0.19 | 3.8 |
[GFG+Li]+ | 5.20 | 0.10 | 2.0 | [GGF+K]+ | 5.11 | 0.06 | 1.1 |
[GFG+Na]+ | 5.15 | 0.04 | 0.7 |
Precursor ion(#) | an/ | bn/ | yn/ | Other |
---|---|---|---|---|
[G3+H]+ | a2 | b1, b2 | y1, y2 | [#-H2O]+ |
[G3+Li]+ | a2, | [b2+OH+Li]+ | [#-H2O]+, [#-NH3-H2O]+ | |
[G3+Na]+ | [b2+OH+Na]+ | [#-H2O]+, [#-NH3]+ | ||
[G3+K]+ | K+ | |||
[G3+2Li-H]+ | a2, | [#-H2O]+ , [#-NH3]+ , [#-NH3- H2O]+ | ||
[G3+2Na-H]+ | [#-H2O]+ | |||
[G3+2K-H]+ | K+ |
Table 2 CID fragment ions formed from protonated or alkali metallated triglycine complexes
Precursor ion(#) | an/ | bn/ | yn/ | Other |
---|---|---|---|---|
[G3+H]+ | a2 | b1, b2 | y1, y2 | [#-H2O]+ |
[G3+Li]+ | a2, | [b2+OH+Li]+ | [#-H2O]+, [#-NH3-H2O]+ | |
[G3+Na]+ | [b2+OH+Na]+ | [#-H2O]+, [#-NH3]+ | ||
[G3+K]+ | K+ | |||
[G3+2Li-H]+ | a2, | [#-H2O]+ , [#-NH3]+ , [#-NH3- H2O]+ | ||
[G3+2Na-H]+ | [#-H2O]+ | |||
[G3+2K-H]+ | K+ |
Precursor ion(#) | an/ | bn/ | yn/ | Other |
---|---|---|---|---|
[GFG+H]+ | a2 | b2 | y2, y2-H2O | |
[GFG+Li]+ | a2* | [b1+OH+Li]+, [b2+OH+Li]+ , | [#-H2O]+,[#-C7H7]+ , [#-H2O-NH3]+ , [#-H2O-C7H7]+ | |
[GFG+Na]+ | [b2+OH+Na]+, [b1+OH+Na]+ ,b2* | [#-H2O]+ | ||
[GFG+K]+ | [#-H2O]+ , K+ | |||
[GFG+2Li-H]+ | [#-H2O]+, [#-H2O-C7H7]+, [#-C7H7]+ | |||
[GFG+2Na-H]+ | [#-H2O]+ , [#-NH3-H2O]+, [#-C7H7]+ |
Table 3 CID fragment ions formed from protonated or alkali metallated GFG complexes
Precursor ion(#) | an/ | bn/ | yn/ | Other |
---|---|---|---|---|
[GFG+H]+ | a2 | b2 | y2, y2-H2O | |
[GFG+Li]+ | a2* | [b1+OH+Li]+, [b2+OH+Li]+ , | [#-H2O]+,[#-C7H7]+ , [#-H2O-NH3]+ , [#-H2O-C7H7]+ | |
[GFG+Na]+ | [b2+OH+Na]+, [b1+OH+Na]+ ,b2* | [#-H2O]+ | ||
[GFG+K]+ | [#-H2O]+ , K+ | |||
[GFG+2Li-H]+ | [#-H2O]+, [#-H2O-C7H7]+, [#-C7H7]+ | |||
[GFG+2Na-H]+ | [#-H2O]+ , [#-NH3-H2O]+, [#-C7H7]+ |
Precursor ion(#) | an/ | bn/ | yn/ | Other |
---|---|---|---|---|
[GGF+H]+ | y2-H2O | |||
[GGF+Li]+ | [b2+OH+Li]+, [b1+OH+Li]+ | [#-H2O]+, [#-NH3- H2O]+ , [#-H2O-C7H7]+ , [#-C7H7]+ | ||
[GGF+Na]+ | [b1+OH+Na] +, [b2+OH+Na]+ | [#-H2O]+ , [#-NH3-H2O]+ , [#-C7H7]+ | ||
[GGF+K]+ | [#-H2O]+ , K+ | |||
[GGF+2Li-H]+ | [#-H2O]+, [#-NH3]+ , [#-NH3-H2O]+ , [#-H2O-C7H7]+ , [#-C7H7]+ | |||
[GGF+2Na-H]+ | [#-H2O]+ , [#-NH3-H2O]+ , [#-C7H7]+ |
Table 4 CID fragment ions formed from protonated or alkali metallated GFG complexes
Precursor ion(#) | an/ | bn/ | yn/ | Other |
---|---|---|---|---|
[GGF+H]+ | y2-H2O | |||
[GGF+Li]+ | [b2+OH+Li]+, [b1+OH+Li]+ | [#-H2O]+, [#-NH3- H2O]+ , [#-H2O-C7H7]+ , [#-C7H7]+ | ||
[GGF+Na]+ | [b1+OH+Na] +, [b2+OH+Na]+ | [#-H2O]+ , [#-NH3-H2O]+ , [#-C7H7]+ | ||
[GGF+K]+ | [#-H2O]+ , K+ | |||
[GGF+2Li-H]+ | [#-H2O]+, [#-NH3]+ , [#-NH3-H2O]+ , [#-H2O-C7H7]+ , [#-C7H7]+ | |||
[GGF+2Na-H]+ | [#-H2O]+ , [#-NH3-H2O]+ , [#-C7H7]+ |
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