Condensation of 2-Substituted-4-formyl-1,2,3-triazole with β-Cyclohexanedione Catalyzed by Mg(ClO4)2

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (6): 1301.

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Condensation of 2-Substituted-4-formyl-1,2,3-triazole with β-Cyclohexanedione Catalyzed by Mg(ClO4)2

LIU Chen-Jiang^1,2,3*, ZHAO Xin-Hai^2,3, WANG Zhao-Shen^2,3

1. Physics and Chemistry Detecting Center,
2. Key Laboratory of Oil and Gas Fine Chemicals of Ministry of Education & Xinjiang Uygur Autonomous Region, School of Chemistry and Chemical Engineering,
3. Urumqi Key Laboratory of Green Catalysis and Synthesis Technology, Xinjiang University, Urumqi 830046, China

Received:2010-10-04 Revised:2010-11-29 Online:2011-06-10 Published:2011-05-10
Contact: LIU Chen-Jiang E-mail:pxylcj@126.com
Supported by:
国家自然科学基金(批准号: 20662009, 20862016)和乌鲁木齐市科技计划项目(批准号: H101133001)资助.

Abstract

Abstract: The condensation reaction of 2-substituted-4-formyl-1,2,3-triazole instead of the ordinary aldehydes with β-cyclohexanedione was investigated by acrylonitrile as a reaction medium, employing Mg(ClO4)2 as the catalyst. It was found that when it was carried out in the presence of Mg(ClO4)2, its selectivity gave the xanthenes. Further study showed that without additional catalyst this reaction could give xanthenediones ring-opening derivatives.

Key words: Xanthenes, Mg(ClO4)2, 2-substituted-4-formyl-1,2,3-triazole, Synthesis

CLC Number:

O621.25

TrendMD:

LIU Chen-Jiang*, ZHAO Xin-Hai, WANG Zhao-Shen. Condensation of 2-Substituted-4-formyl-1,2,3-triazole with β-Cyclohexanedione Catalyzed by Mg(ClO4)2[J]. Chem. J. Chinese Universities, 2011, 32(6): 1301.

References

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Condensation of 2-Substituted-4-formyl-1,2,3-triazole with β-Cyclohexanedione Catalyzed by Mg(ClO4)2

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