Synthesis, Characterization and Luminescence of a New Diamondoid MOF Based on Tetrazole Derivative

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (3): 683.

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Synthesis, Characterization and Luminescence of a New Diamondoid MOF Based on Tetrazole Derivative

QIN Jun-Sheng^1,2, LAN Ya-Qian¹, WANG Hai-Ning¹, LI Lian-Jie¹, WANG Xin-Long¹, SUN Xiu-Yun^2*, SHAO Kui-Zhan¹, SU Zhong-Min^1*

1. Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
2. Department of Applied Chemistry, Jilin Institute of Chemical Technology, Jilin 132022, China

Received:2010-10-14 Revised:2010-11-10 Online:2011-03-10 Published:2011-02-23
Contact: SU Zhong-Min;SUN Xiu-Yun E-mail:zmsu@nenu.edu.cn;sunxiuyun1989@sina.com
Supported by:
国家自然科学基金(批准号: 20901014, 21001020)、长江学者和创新团队发展计划(批准号: IRT0714)、吉林省科技发展计划青年基金(批准号: 20090125, 20090129)、东北师范大学“十一五”科技创新培育基金(批准号: NENU-STC08019)、教育部新教师博士点基金(批准号: 20090043120004)、国家博士后基金(批准号: 20901014)及东北师范大学博士后基金资助.

Abstract

Abstract: A self-assembly reaction between the ligand 5-Amino-tetrazole (HATZ) and zinc(II) nitrate enables the formation of Zn(ATZ)2?DMA (1), which is characterized by X-ray powder diffraction (XRPD), IR spectrum and elemental analysis. Single-crystal X-ray analysis indicates that 1 exhibits a 3D microporous four-connected diamondoid (dia) topology with the channel dimensions of about 12.7 ? × 8.9 ? along the [100] direction. PLATON calculations show void space of ca. 53.5% per unit cell. The luminescent spectrum of 1 shows a strong blue fluorescence at room temperature.

Key words: Metal-organic framework, Tetrazole, Diamondoid topology, Luminescence

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QIN Jun-Sheng, LAN Ya-Qian, WANG Hai-Ning, LI Lian-Jie, WANG Xin-Long, SUN Xiu-Yun*, SHAO Kui-Zhan, SU Zhong-Min*. Synthesis, Characterization and Luminescence of a New Diamondoid MOF Based on Tetrazole Derivative[J]. Chem. J. Chinese Universities, 2011, 32(3): 683.

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Synthesis, Characterization and Luminescence of a New Diamondoid MOF Based on Tetrazole Derivative

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