Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien)(H2O)3]2[Ni(Hdien)2]{[Ni(dien)]2·Ni4(H2O)2(GeW9O34)2}·10H2O

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (3): 571.

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Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien)(H2O)3]2[Ni(Hdien)2]{[Ni(dien)]2·Ni4(H2O)2(GeW9O34)2}·10H2O

LI Xin-Xiong, FANG Wei-Hui, YANG Guo-Yu*

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:2010-11-02 Revised:2010-11-22 Online:2011-03-10 Published:2011-02-23
Contact: YANG Guo-Yu E-mail:ygy@fjirsm.ac.cn
Supported by:
国家“九七三”计划项目(批准号： 2011CB932504)、国家自然科学基金(批准号： 50872133)和国家杰出青年基金(批准号： 20725101)资助.

Abstract

Abstract: A novel organic-inorganic hybrid germanotungstate [Ni(dien)(H2O)3]2[Ni(Hdien)2] -{[Ni(dien)]2Ni4(H2O)2(GeW9O34)2}?10H2O (1) (dien = diethylenetrimine) has been synthesized under hydrothermal conditions and characterized by IR spectroscopy, TGA, elemental analysis, Energy-Dispersive X-ray Spectroscopy (EDS) and single-crystal X-ray structural analysis. Crystal data for 1: Triclinic, P-1, a = 11.937(3) ?, b = 14.323(3) ?, c = 16.394(4) ?, α = 93.424(2)o, β = 96.058(3)o, γ = 109.758(4)o, V = 2609.4(10) ?3, Z = 1. X-ray crystallographic study reveals that 1 was built from [Ni(dien)]2+ decorated Weakley- type sandwich polyoxoanion linked by [Ni(Hdien)2]4+ cations to form a 1-D linear structure, which further stack 3-D network.

Key words: Hydrothermal synthesis, Crystal structure, Organic-inorganic hybrid, Lacunary polyoxometalates, Sandwich, Nickel, Keggin

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LI Xin-Xiong, FANG Wei-Hui, YANG Guo-Yu*. Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien)(H2O)3]2[Ni(Hdien)2]{[Ni(dien)]2·Ni4(H2O)2(GeW9O34)2}·10H2O[J]. Chem. J. Chinese Universities, 2011, 32(3): 571.

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Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien)(H2O)3]2[Ni(Hdien)2]{[Ni(dien)]2·Ni4(H2O)2(GeW9O34)2}·10H2O

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