Selective Interaction Based on Complex [Ru(phen)2(H2biim)](PF6)2 and Anions

Abstract

Abstract: A new anion sensor[Ru(phen)₂(H₂biim)](PF₆)₂(1) has been developed, where the Ru/(Ⅱ)-phen moiety acts as a chromophore and H₂biim ligand as an anion receptor via the formation of hydrogen bonds or deprotonation. A systematic investigation shows that complex 1 is an eligible sensor for various anions. It donates hydrogen bonds to the Cl^-, Br^-, I^-, NO₃^-, HSO₄^- and H₂PO₄^-anions, and further actualize mono proton transfer to OAc^- anion via the formation of a robust, cyclic hydrogen bonding system and turns the color from yellow to orange brown. In the case of F^-, stepwise deprotonation of the two N—H fragments occurs due to the formation of a highly stable HF₂^- anion, resulting in color change from yellow to purple, which can be distinguished by naked-eye.

Key words: Anion-selected recognition, Hydrogen bonding, Proton transfer

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CUI Ying*, YE Bao-Hui, NIU Yan-Li, ZHONG Yong-Rui. Selective Interaction Based on Complex [Ru(phen)₂(H₂biim)](PF₆)₂ and Anions[J]. Chem. J. Chinese Universities, 2010, 31(9): 1706.

References

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Selective Interaction Based on Complex [Ru(phen)₂(H₂biim)](PF₆)₂ and Anions

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