Synthesis and Characterization of Metallofullerene Derivatives La@C82-(C4N2H8)mHn

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (10): 1976.

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Synthesis and Characterization of Metallofullerene Derivatives La@C82-(C4N2H8)mHn

DAI Fu-Cai1,3, CHANG Fei1*, REN Tong-Xiang2, SUN Bao-Yun2*

1. College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot 010021, China;
2. CAS Key Lab for Biomedical Effects of Nanomaterials & Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;
3. College of Chemistry and Materials Science, Langfang Teachers College, Langfang 065000, China

Received:2010-03-22 Online:2010-10-10 Published:2010-10-10
Contact: CHANG Fei, E-mail: chfei@pku.org.cn; SUN Bao-Yun, E-mail: sunby@ihep.ac.cn
Supported by:
中国科学院百人计划、中国科学院高能物理研究所创新基金(批准号: K651551U11, H75453BOU2)和廊坊师范学院项目(批准号: LSZQ200901)资助.

Abstract

Abstract: Metallofullerene derivatives offer the opportunity to produce novel and advanced materials. In this work, we presented the synthesis of metallofullerene piperazine derivatives under different conditions by changing the temperature, light and ratio of the reactants. Three metallofullerene piperazine derivatives [La@C82-C4N2H8, La@C82-C4N2H8-H8, and La@C82-(C4N2H8)2-H6] were separated and confirmed by MALDI-TOF-MS, UV-Vis-NIR and FTIR. Compared with the hollow fullerene C60, we found that metallofullerene showed higher reactivity than C60 and produced different derivatives. The mechanism of the reaction was discussed.

Key words: Metallofullerene, Derivative, MALDI-TOF-MS, UV-Vis-NIR spectrum, FTIR spectrum

TrendMD:

DAI Fu-Cai, CHANG Fei*, REN Tong-Xiang, SUN Bao-Yun*. Synthesis and Characterization of Metallofullerene Derivatives La@C82-(C4N2H8)mHn[J]. Chem. J. Chinese Universities, 2010, 31(10): 1976.

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Synthesis and Characterization of Metallofullerene Derivatives La@C82-(C4N2H8)mHn

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