Synthesis, Structure and Catalysis Performance of Complex [Ni(qina)2(H2O)2]·2DMSO

Abstract

Abstract:

A single crystal complex [Ni(qina)₂(H₂O)₂]·2DMSO(Hqina＝quinaldinic acid, DMSO=dimethyl sulfoxide) was synthesized at room temperature by the solvent substitution method, which belongs to monoclinic system with space group C₂/m. Two qina ligands chelate a nickel(Ⅱ) ion by O and N atoms and two H₂O coordinate a Ni(Ⅱ) ion by two O atoms at an axis. The complex formed inerratic octahedron configuration, and H bonds, π-π stacking were observed between the molecules. 1-Naphthyl acetate hydrolysis velocity has been remarkably enhanced by the title complex, when the concentration of the title complex was at 1.0×10^-4 mol/L, pH 8.44. The enhancement multiple was 365.

Key words: Complex, Nickel(Ⅱ) ion, Quinaldinic acid, Catalysis activity

TrendMD:

WANG Chuan-Sheng, WU Qiong, ZHU Ming-Chang, GAO En-Jun*. Synthesis, Structure and Catalysis Performance of Complex [Ni(qina)₂(H₂O)₂]·2DMSO[J]. Chem. J. Chinese Universities, 2009, 30(5): 862.

References

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Synthesis, Structure and Catalysis Performance of Complex [Ni(qina)₂(H₂O)₂]·2DMSO

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