Chem. J. Chinese Universities

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Investigation of Degradation Behavior of Polymer on Surface of Film Due to the Existence of Monochromatic X-ray

YOU Ji-Chun1, LI Xin-Lin2, SHI Tong-Fei1*, SU Zhao-Hui1*, AN Li-Jia1   

    1. State Key Laboratory of Polymer Physics and Chemistry,
    2. National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  • Received:2008-03-20 Revised:1900-01-01 Online:2008-07-10 Published:2008-07-10
  • Contact: SHI Tong-Fei,SU Zhao-Hui

Abstract: Degradation and its temperature dependence of poly(methyl methacrylate)(PMMA) in the blend film of PMMA/SAN were investigated via in-situ X-ray photoelectron spectroscopy(XPS). The results show that thermal degradation of PMMA takes place at 185, 130, 80 ℃ and even room temperature due to the existence of monochromatic X-ray. Furthermore, the degradation rate depends crucially on the experiment temperature.

Key words: Monochromatic X-ray, Degradation, X-ray photoelectron spectroscopy, Surface of film

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