Some Progresses in Mechanistic Studies on Surface-Enhanced Raman Scattering

Chem. J. Chinese Universities

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Some Progresses in Mechanistic Studies on Surface-Enhanced Raman Scattering

DING Song-Yuan, WU De-Yin*, YANG Zhi-Lin, REN Bin, XU Xin, TIAN Zhong-Qun*

State Key Laboratory of Physical Chemistry of Solid Surfaces and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Received:2008-11-03 Revised:1900-01-01 Online:2008-12-10 Published:2008-12-10
Contact: WU De-Yin, TIAN Zhong-Qun

Abstract

Abstract: In order to further develop surface-enhanced Raman spectroscopy to a versatile and ultra-sensitive diagnostic tool for surface, analytical, life and materials sciences, it is highly desirable to comprehensively reveal the mechanism of surface-enhanced Raman scattering(SERS). In this review article, emphasis is put on recent work of our group on the chemical enhancement(CE) mechanism. Three types of CE are classified as the enhancement by chemical-bonding, surface complex or photo-induced charge transfer. The electromagnetic(EM) field enhancement mechanism will then be introduced briefly, although it is to be considered the major contribution to SERS. Finally, a prospect of establishing the unified theory, that combines the CE and EM mechanism, will be discussed.

Key words: Surface-enhanced Raman scattering(SERS), Chemical enhancement, Electromagnetic enhancement, Unified theory

CLC Number:

O641

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DING Song-Yuan, WU De-Yin*, YANG Zhi-Lin, REN Bin, XU Xin, TIAN Zhong-Qun*. Some Progresses in Mechanistic Studies on Surface-Enhanced Raman Scattering[J]. Chem. J. Chinese Universities, doi: .

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Some Progresses in Mechanistic Studies on Surface-Enhanced Raman Scattering

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