Chem. J. Chinese Universities

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Synthesis and Characterization of 2,5-Bis(2-phenanthrenyl)-thieno[3,2-b]thiophene and Its Application in Organic Thin-film Transistors

TIAN Hong-Kun1,2, SHI Jian-Wu1,2, YAN Dong-Hang1, WANG Li-Xiang1, GENG Yan-Hou1, WANG Fo-Song1
  

    1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Inst
      itute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
    2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China
  • Received:2005-12-05 Revised:1900-01-01 Online:2006-09-10 Published:2006-09-10
  • Contact: GENG Yan-Hou

Abstract: Synthesis and characterization of 2,5-bis(2-phenanthrenyl)-thieno[3,2-b]thiophene(PhTT) were reported. The compound exhibits a great thermal stability. Absorption measurements and electrochemical characterization revealed that PhTT has a relative broad bandgap and low HOMO(the highest occupied molecular orbital) level. The field-effect mobility(μFET) of PhTT from top-contact thin film transistors was 0.021 cm2/(V·s). The thin film transistors of PhTT show a good environmental stability.

Key words: Phenanthrene, Thieno[3,2-b]thiophene, Organic semiconductors, Thin film transistors(TFTs)

CLC Number: 

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