Synthesis and Crystal Structure of Azaanalog of Copper Phthalocyanine

Chem. J. Chinese Universities

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Synthesis and Crystal Structure of Azaanalog of Copper Phthalocyanine

JIANG Wen-Hai¹, WANG Xu², MA Chun-Yu³, YU Shu-Kun¹, YE Kai-Qi², CHANG Yu-Chun^1,3, DU Guo-Tong^1,3

1. State Key Laboratory on Integrated Optoelectronics, Jilin University, Changchun 130012, China;
2. Key Laboratory for Superamolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130012, China;
3. State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Dalian University of Technology, Dalian 116023, China

Received:2006-02-22 Revised:1900-01-01 Online:2006-12-10 Published:2006-12-10
Contact: DU Guo-Tong

Abstract

Abstract: The azaanalog of copper phthalocyanine(aza-CuPc) complex C₂₄H₈CuN₁₆ was prepared by the so-lid phase synthesis technology and its single crystals was characterized by high power X-ray from the synchrotron radiation. The crystal belongs to monoclinic system, space group P2₁/n with a=1.612 3(3) nm, b=0.529 40(11) nm, c=1.906 4(4) nm, β=105.25(3)°, V=1.569 9(5) nm, Z=2, M_r=584.00, D_c=1.235 g/cm³, F(000)=586, the final R=0.063 1 and wR=0.153 9 for 757 observed reflections with I>2σ(I), GOF=1.340.

Key words: Solid phase synthesis, Azaanalog of copper phthalocyanine, Synchrotron radiation, Crystal structure

CLC Number:

O614
O621.15

TrendMD:

JIANG Wen-Hai¹, WANG Xu², MA Chun-Yu³, YU Shu-Kun¹, YE Kai-Qi², CHANG Yu-Chun^1,3, DU Guo-Tong^1,3
. Synthesis and Crystal Structure of Azaanalog of Copper Phthalocyanine[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Crystal Structure of Azaanalog of Copper Phthalocyanine

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