Preparation of Single Crystal CaSO4 Nanotubes: A Nanotube Growing Route for Compound with Non-layered Structure

Abstract

Abstract: Single-crystal CaSO₄ nanotubes were prepared via a solvothermal process by using lamellar {Ti-O-Ti} polymer coupling oleic acid as the frame developing agent .The nanotubes were characterized by X-ray diffraction(XRD), energy dispersive X-ray analysis(EDX), transmission electron microscopy(TEM) and convergent beam electron diffraction(CBED). Lattice parameters of CaSO₄ single-crystal nanotubes are consistent with the standard values in JCPDS card of CaSO₄, which belongs to a hexagonal system, space group P3m1(164). The morphology of CaSO₄ nanotubes is mainly straight with inner hollow. The outer and inner diameters of the nanotubes are about 30 nm and 10 nm, respectively, and lengths reach up to 3.0 μm. The formation mechanism for CaSO₄ nanotubes was also discussed .This paper presents a promising solvothermal method for the preparation of nanotubes of self-nonlayered ionic crystals in terms of rolling of layer-by-layer grown from frame developing agent of lamellar Ti-O-Ti polymer coupling oleic acid.

Key words: Ti-O-Ti polymer coupling oleic acid, Solvothermal method, Calcium sulphate, Nanotube, Frame developing agent

CLC Number:

O614

TrendMD:

GAO Yuan-Hao, LIU Jin, NIU He-Lin. Preparation of Single Crystal CaSO₄ Nanotubes: A Nanotube Growing Route for Compound with Non-layered Structure[J]. Chem. J. Chinese Universities, 2005, 26(9): 1594.

References

[1] Iijima S..Nature[J],1991,354(6348):56—58 [2] R inzler A.G.,Hafner J.H.,N ikolaev P.etal..Science[J],1995,269(5230):1550—1553 [3] Kong J.,Fanklin N.R.,Zhou C.W.etal..Science[J],2000,287(5453):622—625 [4] Kim P.,L ieber C.M..Science[J],1999,286(5447):2148—2150 [5] de Heer W.A.,Chatelain A.,Ugarte D..Science[J],1995,270(5293):1179—1180 [6] Nagy G.,Levy M.,Scarmozzino R.etal..App l.Phys.Lett.[J],1998,73(4):529—531 [7] Zhang Y.F.,Tang Y.H.,W ang N.etal..App l.Phys.Lett.[J],1998,72(15):1835—1837 [8] Moriyoshi Y.,Shim izu Y.,W atanabe T..Thin Solid Film s[J],2001,390(1—2):26—30 [9] Ma R.,Bando Y.,Sato T..Chem ical Physics Letters[J],2001,337(1—3):61—64 [10] Bando Y.,Ogawa K.,Golberg D..Chem ical Physics Letters[J],2001,347(4—6):349—354 [11] Han W.Q.,Cum ings J.,Huang X.S.etal..Chem ical Physics Letters[J],2001,346(5—6):368—372 [12] Tenne R.,Margulis L.,Genut M.etal[J],1992,360(6403):444—446 [13] Feldman Y.,Margulis L.,Homyonfer M.etal..H igh Temperature Materials and Processes[J],1996,15(3):163—169 [14] Bai X.D.,Guo J.D.,Yu J.etal..App lied Physics Letters[J],2000,76(15):2624—2626 [15] Nath M.,Rao C.N.R..Chem ical Communications[J],2001,21:2236—2237 [16] Chop ra N.G.,Luyren J.,Cherry K.etal.Science[J],1995,269(5226):966—967 [17] Hollingsworth J.A.,Poojary D.M.,Clearfied A.etal..J.Am.Chem.Soc.[J],2000,122(14):3562—3563 [18] A livisatos A.P.Scientific American[J],2001,285(3):66—73 [19] CHEN Long-W u(陈龙武),GAN L i-Hua(甘礼华),XU Zi-J ie(徐子颉).Chem.J.Chinese Universities(高等学校化学学报)[J],2001,22(11):1916—1918 [20] ZHANG Peng-Yi(张彭义),YU Gang(余刚),J IANG Zhan-Peng(蒋展鹏).Environ.Sci.Progress(环境科学进展)[J],1998,6(5):50—56 [21] ZHANG Xu(张旭),X IE Yi(谢芳),XU Fen(徐芬)etal..Chinese Journal of Inorganic Chem istry(无机化学学报)[J],2003,19(1):77—80 [22] WU Q ing-Sheng(吴庆生),ZHENG Neng-W u(郑能武),D ING Ya-Ping(丁亚平).Chem.J.Chinese Universities(高等学校化学学报)[J],2001,22(6):898—900 [23] GAO Yuan-Hao(高远浩),N IU He-L in(牛和林),CHEN Q ia-W ang(陈乾旺).Chinese Journal of Inorganic Chem istry(无机化学学报)[J],2003,19(1):37—40

Preparation of Single Crystal CaSO₄ Nanotubes: A Nanotube Growing Route for Compound with Non-layered Structure

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