Hydrothermal Synthesis and Characterization of a Manganese(Ⅱ)-substituted Aluminum Phosphate Mn3Al6(PO4)12·4tren·11H2O with 12-Membered Ring Channel Open Framework

Abstract

Abstract: A three-dimensional manganese(Ⅱ)-substituted aluminum phosphate, Mn₃Al₆(PO₄)₁₂·4tren·11H₂O[tren is tris(2-aminoethyl)amine], was synthesized hydrothermally. Its structure was determined by single-crystal X-ray diffraction analysis and further characterized by X-ray powder diffraction, ICP, TG analyses and magnetic susceptibility measurements. It crystallizes in the cubicsystem, space group I-43m(No. 217) with a=1.683 51(4)_nm, V=4.771 4(2) nm³, Z=2, R₁=0.043 9 and wR₂=0.132 4[I>2σ(I)]. The open framework built up from strict alternation of TO₄/AlO₄ and PO₄ tetrahedra through corner-sharing vertex oxygen atoms. It contains 12-membered ring channels. The Mn atoms of the framework are bivalence proved by magnetic susceptibility measurements.

Key words: Hydrothermal synthesis, Aluminum phosphate, Structure, Manganese(Ⅱ)-substitution

CLC Number:

O614

TrendMD:

SHI Lei, LI Ji-Yang, DUAN Fang-Zheng, YU Ji-Hong, LI Yi, XU Ru-Ren . Hydrothermal Synthesis and Characterization of a Manganese(Ⅱ)-substituted Aluminum Phosphate Mn₃Al₆(PO₄)₁₂·4tren·11H₂O with 12-Membered Ring Channel Open Framework[J]. Chem. J. Chinese Universities, 2005, 26(5): 819.

[1]	JIANG Bowen, CHEN Jingxuan, CHENG Yonghua, SANG Wei, KOU Zongkui. Recent Progress of Single-atom Materials in Electrochemical Biosensing [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220334.
[2]	WANG Sicong, PANG Beibei, LIU Xiaokang, DING Tao, YAO Tao. Application of XAFS Technique in Single-atom Electrocatalysis [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220487.
[3]	WU Yushuai, SHANG Yingxu, JIANG Qiao, DING Baoquan. Research Progress of Controllable Self-assembled DNA Origami Structure as Drug Carrier [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220179.
[4]	LI Lin, QI Fenglian, QIU Lili, MENG Zihui. Dynamic Amorphous Photonic Structure Patterns Assembled by Hexagonal Magnetic Nanosheets [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220123.
[5]	JIA Yanggang, SHAO Xia, CHENG Jie, WANG Pengpeng, MAO Aiqin. Preparation and Lithium Storage Performance of Pseudocapacitance-controlled Perovskite High-entropy Oxide La（Co_0.2Cr_0.2Fe_0.2Mn_0.2Ni_0.2）O₃ Anode Materials [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220157.
[6]	YANG Dan, LIU Xu, DAI Yihu, ZHU Yan, YANG Yanhui. Research Progress in Electrocatalytic CO₂ Reduction Reaction over Gold Clusters [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220198.
[7]	ZHAO Yingzhe, ZHANG Jianling. Applications of Metal-organic Framework-based Material in Carbon Dioxide Photocatalytic Conversion [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220223.
[8]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[9]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[10]	CHEN Weiqin, LYU Jiamin, YU Shen, LIU Zhan, LI Xiaoyun, CHEN Lihua, SU Baolian. Preparation of Organic Hybrid Mesoporous Beta Zeolite for Alkylation of Mesitylene with Benzyl Alcohol [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220086.
[11]	ZHU Kai, LI Jie, WU Xiaoyi, HU Weiwei, WU Dongmei, YU Chengxiao, GE Zhiwei, YE Xingqian, CHEN Shiguo. Combined PGC-Triple-Tof-MS Enables the Separation， Identification of Sugar Beet Pectin Derived Oligomers [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220023.
[12]	GU Yu, XI Baojuan, LI Jiangxiao, XIONG Shenglin. Structure Regulation of Single-atom Catalysts in Oxygen Reduction Reactions [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220036.
[13]	XU Siran, YIN Hengbo, XUE Dongping, XIA Huicong, ZHAO Shuyan, YAN Wenfu, MU Shichun, ZHANG Jianan. Atomically Dispersed Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction Reaction [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220028.
[14]	XIA Tian, WAN Jiawei, YU Ranbo. Progress of the Structure-property Correlation of Heteroatomic Coordination Structured Carbon-based Single-atom Electrocatalysts [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220162.
[15]	GUO Jinchang, LIU Fanglin. Planar Pentacoordinate Silicon and Germanium in XBe₅H₆（X=Si， Ge） Clusters [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210807.

Hydrothermal Synthesis and Characterization of a Manganese(Ⅱ)-substituted Aluminum Phosphate Mn₃Al₆(PO₄)₁₂·4tren·11H₂O with 12-Membered Ring Channel Open Framework

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments