Chem. J. Chinese Universities ›› 2005, Vol. 26 ›› Issue (12): 2207.

• Articles • Previous Articles     Next Articles

NTCR Effect of BaTiO3-based PTC Ceramics Penetrated by Rare Earth

HAO Su-E*, SUN Liang, HUANG Jin-Xiang, WEI Yong-De   

  1. Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China
  • Received:2005-02-03 Online:1905-03-14 Published:1905-03-14
  • Contact: HAO Su-E;E-mail:haosue@hit.edu.cn

Abstract:

The modified BaTiO3-based PTC ceramics were prepared by gaseous penetration of rare earth La, and the change laws of the resistivity at room temperature and the temperature- resistivity properties were studied. The experimental results show that the modified BaTiO3 -based PTC ceramics after La penetration have a significant decrease in resistivity at room temperature, which decreases from 2.7×109 to 220 Ω·m,  and the resistivity decreases progressively from 220 to 5.8 Ω·m in the temperatures range from 25 ℃ to 500 ℃, which indicates a significant NTCR effect. Through analyses of XRD, SEM, EDAX and the dielectric properties of the BaTiO3-based PTC ceramics penetrated by La, the forming mechanism of the NTCR effect was explored, and the physical structure model of the NTCR effect was established.

Key words: Rare earth; Gaseous penetration; NTCR effect; BaTiO3 ceramics, Rare earth, Gaseous penetration, NTCR effect, BaTiO3 ceramics

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