Application of ABEEM-σπ Model to Stereoselectivity in Classical Diels-Alder Reactions

Chem. J. Chinese Universities ›› 2005, Vol. 26 ›› Issue (11): 2082.

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Application of ABEEM-σπ Model to Stereoselectivity in Classical Diels-Alder Reactions

LI Ming-Nan, YANG Zhong-Zhi

Department of Chemistry,Liaoning Normal University,Dalian 116029,China

Received:2004-12-09 Online:2005-11-10 Published:2005-11-10

Abstract

Abstract: Diels-Alder reaction has a huge application value due to their high stereoselectivity.The reactive region of this kind of cycloaddition includes not only atoms but also the important π bond zones.In this article,we utilized the ABEEM-σπ model to research this kind of reactions,and through the regional softnesses of both the atoms and π bonds,which were calculated by this model,we interpret properly the stereoselectivity of the typical Diels-Alder reaction.

Key words: ABEEM-σ&pi, model, Diels-Alder reaction, Local softness

CLC Number:

O641

TrendMD:

LI Ming-Nan, YANG Zhong-Zhi. Application of ABEEM-σπ Model to Stereoselectivity in Classical Diels-Alder Reactions[J]. Chem. J. Chinese Universities, 2005, 26(11): 2082.

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Application of ABEEM-σπ Model to Stereoselectivity in Classical Diels-Alder Reactions

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