Synthesis, Structure and Property of a 2D Network of Silver Complex

Abstract

Abstract: A new coordination complex, [Ag(IIMB)N₃], was prepared by self-assembly of asymmetric ligand 1-(1-imidazolyl)-4-(imidazol-1-ylmethyl)benzene(IIMB) with [Ag(NH₃)₂]N₃. The crystal structural analysis indicates that the structure of the complex contains fifty-two-membered macrometallacyclic rings, and the complex crystallizes in monoclinic system, space group of P2₁/c with a=0.739 8(1) nm, b=1.045 1(1) nm, c=1.812 4(2)nm, β=91.65(1)°, V=1.400 7(3) nm³, Z=4, D_c=1.774 g/cm³, F(000)=744, R=0.050 5, wR=0.084 0. It is notable that the azide ion bridges two silver(Ⅰ) atoms in end-on fashion.

Key words: Silver(Ⅰ) complex, Azide, Ligand containing imidazolyl, C_H…%π% interaction

CLC Number:

O641.4

TrendMD:

ZHU Hui-Fang, FAN Jian, SUN Wei-Yin . Synthesis, Structure and Property of a 2D Network of Silver Complex[J]. Chem. J. Chinese Universities, 2005, 26(1): 19.

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Synthesis, Structure and Property of a 2D Network of Silver Complex

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