Synthesis of Metal Porphyrins Bonded with Salicylic Acid and Their Interaction with Bovine Serum Albumin

Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (9): 1604.

• Articles • Previous Articles Next Articles

Synthesis of Metal Porphyrins Bonded with Salicylic Acid and Their Interaction with Bovine Serum Albumin

JIA Tao¹, WANG Kai^1,2, BAO Xiao-Ping¹, ZHAO Yi-Mei³, LI Zao-Ying¹

1. College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China;
2. Department of Pharmaceutical Technology, Wuhan Institute of Chemical Techology, Wuhan 430074, China;
3. Institute of RHK(Group) Co. Ltd., Wuhan 430070, China

Received:2003-11-11 Online:2004-09-24 Published:2004-09-24

Abstract

Abstract: A synthetic method of porphyrins bonded with salicylic substituents was described. Reaction of bromoalkoxyphenyl porphyrin(1) with salicylic acid gave free porphyrins 2 and 3. Treatment of porphyrins 2 and 3 with Co(OCOCH₃)₂ respectively, afforded metalloporphyrins 4 and 5. These new compounds were confirmed by ¹H NMR, IR, UV-Vis, MS and elemental analysis, and their interaction with bovine serum albumin(BSA) in fluorescence spectrum was observed.

Key words: Metalloporphyrin, Salicylic acid, Synthesis, Bovine serum albumin(BSA), Fluorescence spectrum

CLC Number:

O614

TrendMD:

JIA Tao, WANG Kai, BAO Xiao-Ping, ZHAO Yi-Mei, LI Zao-Ying . Synthesis of Metal Porphyrins Bonded with Salicylic Acid and Their Interaction with Bovine Serum Albumin[J]. Chem. J. Chinese Universities, 2004, 25(9): 1604.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[3]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[4]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[5]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	QIU Liqi, YAO Xiangyang, HE Liangnian. Visible-light-driven Selective Reduction of Carbon Dioxide Catalyzed by Earth-abundant Metalloporphyrin Complexes [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220064.
[9]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[10]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[11]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[12]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[13]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[14]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.
[15]	TAN Yuling, YANG Ling, YU Hong, NI Chunyan, LANG Jianping. Progress of the Synthesis of High-Nuclearity Ag/S Nanoclusters [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210476.

Synthesis of Metal Porphyrins Bonded with Salicylic Acid and Their Interaction with Bovine Serum Albumin

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments