Self-assembly Synthesis,Structure Characterization and Antibacterial Activity of Complexes （ABOB）4[H2V10O28]·9H2O and （ABOB）6[V10O28] ·4H2O（ABOB=Moroxydine）

Abstract

Abstract: Two novel complexes（C₆H₁₄ N₅O）₄ [H₂V₁₀ O₂₈ ] ·9H₂O（1） and （C₆H₁₄ N₅O）₆ [V₁₀ O₂₈ ] ·4H₂O（2） were synthesized by the self-assembly of decavanadate and ABOB in aqueous medium at different pH values for the first time. Their structures were determined by means of IR, ⁵¹V NMR and X-ray diffraction. Complex 1 crystallizes in the monoclinic system,space group P2₁/n with a= 1.339 58（8） nm ,b=1.482 62（9） nm,c=1.713 53（14） nm,β=111.450（3）°,V=3.167 5（4） nm³,Z=2,R₁=0.050 0,wR₂=0.143 4. Complex 2 crystallizes in the monoclinic system,space group P2₁/n with a=11.698 8（7） nm,b=2.407 94（11） nm,c=1.313 20（10） nm,β=91.635（2）°,V=3.697 8（4） nm³,Z=2,R₁=0.039 7,wR₂=0.100 8. The X-ray crystallographic study shows that the crystals are constructed by electrostatic forces and hydrogen bond interactions among decavanadate anions,protonated ABOB cations and lattice water molecules. The polyanions,cations and water molecules arrayed in a good order to form 2D layered arrangements along the c axis in complex 1. The antibacterial trial shows that the two complexes show an good antibacterial activity against Staphylococcus aureus,Staphylococcus epidermis,MRSA and MRSE.

Key words: Decavanadate, Moroxydine(ABOB), Self-assembly, Synthesis, Antibacterial activity

CLC Number:

O614

TrendMD:

LIU Shu-Xia, ZHAI Hong-Ju, PENG Jun, LI De-Hui, DAI Zhi-Min, WANG En-Bo, HU Ning-Hai, JIA Heng-Qing. Self-assembly Synthesis,Structure Characterization and Antibacterial Activity of Complexes （ABOB）₄[H₂V₁₀O₂₈]·9H₂O and （ABOB）₆[V₁₀O₂₈] ·4H₂O（ABOB=Moroxydine）[J]. Chem. J. Chinese Universities, 2004, 25(6): 997.

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Self-assembly Synthesis,Structure Characterization and Antibacterial Activity of Complexes （ABOB）₄[H₂V₁₀O₂₈]·9H₂O and （ABOB）₆[V₁₀O₂₈] ·4H₂O（ABOB=Moroxydine）

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