Synthesis,Characterization,Liquid Crystal and Photoluminescent Properties of Surfactant Ruthenium(Ⅱ) Complex

Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (6): 1002.

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Synthesis,Characterization,Liquid Crystal and Photoluminescent Properties of Surfactant Ruthenium(Ⅱ) Complex

LI Bin^1,2, FU Chun-Yan¹, SU Zhong-Min¹, LIU Jing-Fu¹

Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Received:2003-08-05 Online:2004-06-24 Published:2004-06-24

Abstract

Abstract: A new surfactant Ru（Ⅱ） complex [Ru（bpy）₂（d19-phen）] Cl₂（bpy=2,2′-bipyridine,d19-phen=4,7-dinonadecyl-1,10-phenanthroline） was synthesized and characterized by elemental analysis, mass spectra and ¹H NMR. The complex-water mixture displays lyotropic liquid crystalline behaviour. Photophysical properties of the complex was investigated. The complex shows a good luminescence property with a high quantum yield.

Key words: Surfactant Ru(Ⅱ) complex, Photophysics, Lyotropic liquid crystalline

CLC Number:

O627.4

TrendMD:

LI Bin, FU Chun-Yan, SU Zhong-Min, LIU Jing-Fu. Synthesis,Characterization,Liquid Crystal and Photoluminescent Properties of Surfactant Ruthenium(Ⅱ) Complex[J]. Chem. J. Chinese Universities, 2004, 25(6): 1002.

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Synthesis,Characterization,Liquid Crystal and Photoluminescent Properties of Surfactant Ruthenium(Ⅱ) Complex

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