Syntheses and Characterization of Poly(olefin-co-ester)s

Abstract

Abstract: A series of copoly(olefin-co-ester)s were synthesized and characterized by starting from cyclooctene, cyclooctadiene or nobornene with ethanediol di(10-undecenoate) Via metathesis copolymerization and hydrogenation reaction. The yield, molecular weight, polar comonomer content and melting temperature of the poly(olefin-ester)s can be controlled by the change of polymerization reaction condition. Two step procedure is preferable to prepare high molecular weight poly(olefin-ester)s with a high polar monomer content and a high melting temperature.

Key words: Metathesis polymerization, Copolymerization, Poly(olefin-co-ester)s

CLC Number:

O631.5

TrendMD:

ZHAO Xian-Liang, LIU Jing-Yu, LI Yue-Sheng . Syntheses and Characterization of Poly(olefin-co-ester)s[J]. Chem. J. Chinese Universities, 2004, 25(3): 585.

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Syntheses and Characterization of Poly(olefin-co-ester)s

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