Synthesis and Crystal Structure Characterization of a 3D Inorganic-organic Hybrid Framework Microporous Compound Mn3(BTC)2(bpy)(EG)(DMF)·(DMF)·1/3(C2H5OH)

Abstract

Abstract: The title compound Mn₃(BTC)₂(bpy)(EG)(DMF)·(DMF)·1/3(C₂H₅OH)(BTC=1,3,5-benzenetricarboxylic acid, bpy=4,4′-bipyridine, EG=ethylene glycol, DMF=dimethylformamide) was synthesized under mild conditions and its crystal structure was determined by single crystal X-ray diffraction. The compound crystallizes in the monoclinic system and belongs to space group P2₁/n with a= 1.637 2(3) nm, b=1.481 4(3) nm, c=1.838 4(4) nm, β=113.70(3)°, V=4.082 5(14) nm³, Z=4, D_c=1.508 Mg/m³, M_r=958.85, μ=1.001 mm^-1, F(000)=1 920. R₁=0.098 5, wR₂= 0.218 3. Its structure reveals that Mn(Ⅱ) centers and the carboxylate groups of BTC construct 1D O-C-O-Mn chains. Then, adjacent chains are interlinked by benzene rings of BTC to form a novel 3D architecture. It contains eight-membered rings channels that are about 0.8 nm×0.8 nm viewed along the (101) direction. In addition, it is believed that the bpy acts as both an organic ligand and a structure-directing agent in the synthesis of the title compound.

Key words: Inorganic-organic hybrid framework, Microporous compound, Crystal structure

CLC Number:

O614

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FANG Qian-Rong, ZHU Guang-Shan, DING Hong, XUE Ming, XIN Ming-Hong, WU Gang, TIAN Ge, QIU Shi-Lun . Synthesis and Crystal Structure Characterization of a 3D Inorganic-organic Hybrid Framework Microporous Compound Mn₃(BTC)₂(bpy)(EG)(DMF)·(DMF)·1/3(C₂H₅OH)[J]. Chem. J. Chinese Universities, 2004, 25(12): 2218.

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Synthesis and Crystal Structure Characterization of a 3D Inorganic-organic Hybrid Framework Microporous Compound Mn₃(BTC)₂(bpy)(EG)(DMF)·(DMF)·1/3(C₂H₅OH)

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