Hydrothermal Synthesis and Structure Characterization of Double Perovskite-type Oxide, Ba2SmSbO6

Abstract

Abstract: Hydrothermal technique was used for the synthesis of double perovskite-type oxide Ba₂SmSbO₆ and the crystal structure was refined by Rietveld using GSAS software. The Ba₂SmSbO₆ compound has a cubic symmetry(space group Fm3m) with cell parameters a= 0.850 97(20) nm and V= 0.616 23(25) nm³, and it shows an ordered arrangement of Sm and Sb ions. The synthesized Ba₂SmSbO₆ was characterized by XRD, IR, ICP, XPS and ¹²¹Sb Mössbauer spectrum methods. The results indicated that the molar ratio of n(Ba):n(Sm):n(Sb) is closing to 2:1:1, and the antimony valence state is +5.

Key words: Double perovskite-type oxide, Hydrothermal synthesis, Ordered B-site ions

CLC Number:

O613

TrendMD:

ZHENG Wen-Jun, HUANG Hong-Bo, WU Li-Yan, XIA Yuan-Fu . Hydrothermal Synthesis and Structure Characterization of Double Perovskite-type Oxide, Ba₂SmSbO₆[J]. Chem. J. Chinese Universities, 2004, 25(12): 2199.

References

[1] 　Cava R.J.,Batllog B.,K rajew sh i J.J.et al..N ature[J],1988,332:814_815 [2] 　R ao C.N.R.,Cheetham A.K..Science[J],1996,272:369_370 [3] 　Kobyash i .I,K im ura T.,Saw ada H.et al..N ature[J],1998,396:677_679 [4] 　A nderson M.T.,Greenw ood K.B.T aylo r G.A.et al..P rog.So lid State Chem.[J],1993,22(3):197_236 [5] 　FEN G Shou-H ua(冯守华),XU R u-R en(徐如人),PAN G W en-Q in(庞文琴).Ino rgan ic Syn thesis and P reparative Chem istry(无机合成与制备化学)[M],Beijing:Higher Education Publishing House,2001:128_165 [6] 　W AN G D an(王　丹),YU R an-Bo(于然波),FEN G Shou-H ua(冯守华)et al..Chem.J.Ch inese U n iversities(高等学校化学学报)[J],1998,19(2):165_168 [7] 　ZH EN G W en-Jun(郑文君),PAN G W en-Q in(庞文琴).Chem.J.Ch inese U n iversities(高等学校化学学报)[J],1996,17(4):523_526 [8] 　Cava R.J.,Batllog B.,E sp ino sa G.P.et al..N ature[J],1989,339:291_301 [9] 　Kash im a N.,Inoue K.,W ada T.et al..A pp l.Phys.[J],2002,A 74:S805_808 [10] 　H enm i K.,H inatsu Y.,M asak i N.M..J.So lis State Chem.[J],1999,148(2):353_360 [11] 　CAO X i-Zhang(曹锡章),ZHAN G W an-H ui(张婉蕙),DU Yao-Guo(杜尧国).Ino rgan ic Chem istry(无机化学),2nd Ed.[M],Beijing:H igher Education Publish ing House,1983:151 [12] 　L iu R.,Xuan Y.,J ia Y.Q..J.So lid State Chem.[J],1997,134:420_425 [13] 　Casado P.G..Z.A no rg.A llg.Chem.[J],1984,510:194_198 [14] 　Kutty T.R.N.,V ivekanandam R.,Ph ilip S..J.M ater.Sc.i[J],1990,25:3649_3654 [15] 　R am adass R.,Gopalak risnam J.,SastriM.V.C..J.Ino rg.N ucl.Chem.[J],1978,40:1453_1455 [16] 　Zheng W.J.,Pang W.Q.,M eng G.Y..M ater.L ett.[J],1998,37:276_280 [17] 　L avat A.E.,Baran E..J.V ib.Spectro sc.[J],2003,32(2):167_174 [18] 　Standard E sca Spectra of the E lem en ts and L ine Energy Info rm ation,ФCo.,UA S [19] 　L ippen s P.E..So lid State Comm.[J],2000,27(4):399_403 [20] 　HUAN G Hong-Bo(黄红波),ZH EN G W en-Jun(郑文君),W U L i-Yan(武丽艳)et al..N uclear T echn iques(核技术)[J],2004,27(4):256_258 [21] 　Goya G.F.,M ercader R.C.,Causa M.T.et al..J.Phys.:Conden s.M ater.[J],1996,8:8607_8609 [22] 　W akesh im a M.,H arada D.,H inatsu Y..J.So lid State Chem.[J],1999,147:618_624 [23] 　T aira N.,H inatsu Y..J.So lid State Chem.[J],2000,150:31_36 [24] 　Kanaiw a Y.,W akesh im a M.,H inatsu Y..M ater.R es.Bul.l[J],2002,37:1852_1836

Hydrothermal Synthesis and Structure Characterization of Double Perovskite-type Oxide, Ba₂SmSbO₆

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