Synthesis, Crystal Structure and Magnetic Properties of Ni(Ⅱ) Complex with a New Thiazole-substituted Nitronyl Nitroxide

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (7): 1161.

• Preface • Previous Articles Next Articles

Synthesis, Crystal Structure and Magnetic Properties of Ni(Ⅱ) Complex with a New Thiazole-substituted Nitronyl Nitroxide

WANG Li-Ya¹, YANG He-Ping¹, LIAO Dai-Zheng¹, JIANG Zong-Hui^1,2, YAN Shi-Ping¹

1. Department of Chemistry, Nankai University, Tianjin 300071, China;
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Received:2002-12-24 Online:2003-07-24 Published:2003-07-24

Abstract

Abstract: A new nickl(Ⅱ) complex containing the thiazole-substituted nitroxide radical with the formula Ni(NIT2-thz)₂Cl₂(NIT₂-thz=4,4,5,5-tetramethyl-2-(2′-thiazole)imidazolin-1-oxyl-3-oxide) was synthesized and its crystal structure was determined. The magnetic property analysis indicates that there is strong antiferromagnetic interactions between Ni(Ⅱ) and radical(J=-71.82cm^-1).

Key words: Thiazole nitroxide radical, Ni(Ⅱ) complex, Crystal structure, Magnetism

CLC Number:

O635

TrendMD:

WANG Li-Ya , YANG He-Ping, LIAO Dai-Zheng, JIANG Zong-Hui, YAN Shi-Ping . Synthesis, Crystal Structure and Magnetic Properties of Ni(Ⅱ) Complex with a New Thiazole-substituted Nitronyl Nitroxide[J]. Chem. J. Chinese Universities, 2003, 24(7): 1161.

References

Related Articles 15

[1]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[2]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[3]	GUO Biao, ZHAO Chencan, LIU Xinxin, YU Zhou, ZHOU Lijing, YUAN Hongming, ZHAO Zhen. Effects of Surface Hydrothermal Carbon Layer on the Photocatalytic Activity of Magnetic NiFe₂O₄ Octahedron [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220472.
[4]	XU Fei, LI Gangmei, HAN Songde, WANG Guoming. Photochromism and Photomagnetism in Two Dinuclear Lanthanide Complexes [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210337.
[5]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[6]	RUAN Zeyu, DU Shannan, HUANG Guozhang, TONG Mingliang, LIU Junliang. Atropisomerism and Magnetic Properties of an in situ Synthesized Chiral Nickel Complex [J]. Chem. J. Chinese Universities, 2021, 42(3): 709.
[7]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[8]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[9]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[10]	WANG Xiaohui, WANG Kexin, LIU Junping, HONG Xia. Mesoporous-structure Enhanced Photothermal Effect of Fe₃O₄ Superparticles@mesoporous Silica [J]. Chem. J. Chinese Universities, 2019, 40(8): 1586.
[11]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[12]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[13]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[14]	ZHU Lei,HAN Junyan,CHANG Haizhen,QIU Yuyuan,ZHANG Yanan,PENG Danni,HU Wei,MIAO Shaobin. Different Pathways for the Cyclocondensation Reactions of 1,2-Diamine and 1,2-Diketone^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2686.
[15]	LI Zheng, LI Rui, LI Xia. Synthesis, Crystal Structure and Fluorescent Properties of Transition Metal Complexes Constructed with 2-(3'-Carboxyphenoxy)benzoic Acid and N-Donor Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2363.

Synthesis, Crystal Structure and Magnetic Properties of Ni(Ⅱ) Complex with a New Thiazole-substituted Nitronyl Nitroxide

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments